Preprints

Filtering by Subject: Biogeochemistry

A Vision for the Future Low-Temperature Geochemical Data-scape

Susan L. Brantley, Tao Wen, Deb Agarwal, Jeff Catalano, Paul A. Schroeder, Kerstin Lehnert, Charuleka Varadharajan, Julie Pett-Ridge, Mark Engle, Anthony M. Castronova, Rick Hooper, Xiaogang Ma, Lixin Jin, Kenton McHenry, Emma Aronson, Andrew Shaughnessy, Lou Derry, Justin Richardson, Jerad Bales, Eric Pierce

Published: 2020-11-21
Subjects: Biogeochemistry, Computer Sciences, Databases and Information Systems, Earth Sciences, Environmental Sciences, Geochemistry, Geology, Geomorphology, Hydrology, Other Computer Sciences, Other Earth Sciences, Soil Science

Data sharing benefits the researcher, the scientific community, and most importantly, the public by enabling more impactful analysis of data and greater transparency in scientific research. However, like many other scientists, the low-temperature geochemistry (LTG) community has generally not developed protocols and standards for publishing, citing, and versioning datasets. This paper is the [...]

A global Bayesian temperature calibration for lacustrine brGDGTs

Pablo Martinez Sosa, Jess Tierney, Ioana Cristina Stefanescu, Emily Dearing Crampton-Flood, Bryan N Shuman, Cody Routson

Published: 2020-11-13
Subjects: Biogeochemistry, Climate

Despite widespread use of branched glycerol dialkyl glycerol tetraethers (brGDGTs) for paleo-temperature reconstruction, no global calibration for their application in lakes has been generated since improved analytical methods have allowed for the separation of the structural isomers. This is a substantial obstacle for the application of this tool as soil calibrations underestimate temperature [...]

Leaf trait plasticity alters competitive ability and functioning of simulated tropical trees in response to elevated carbon dioxide

Marlies Kovenock, Charles D. Koven, Ryan G. Knox, Rosie A. Fisher, Abigail L. S. Swann

Published: 2020-10-21
Subjects: Biogeochemistry, Climate, Terrestrial and Aquatic Ecology

The response of tropical ecosystems to elevated carbon dioxide (CO$_2$) remains a critical uncertainty in projections of future climate. Here we investigate how leaf trait plasticity in response to elevated CO$_2$ alters projections of tropical forest competitive dynamics and functioning. We use vegetation demographic model simulations to quantify how plasticity in leaf mass per area and leaf [...]

dragon: A New Tool for Exploring Redox Evolution Preserved in the Mineral Record

Stephanie J. Spielman, Eli K. Moore

Published: 2020-07-16
Subjects: Biogeochemistry, Earth Sciences, Physical Sciences and Mathematics

The flow of energy and elements between the geosphere and biosphere can be traced through changing redox chemistry of Earth’s surface. Deep-time trends in the mineral record, including mineral age and elemental composition, reveal a dynamic history of changing redox states and chemical speciation. We present a user-friendly exploratory network analysis platform called dragon (Deep-time Redox [...]

Alkenone isotopes show evidence of active carbon concentrating mechanisms in coccolithophores as aqueous carbon dioxide concentrations fall below 7 µmolL-1

Marcus Peter Sebastian Badger

Published: 2020-07-15
Subjects: Biogeochemistry, Climate, Earth Sciences, Geochemistry, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics

Coccolithophores and other haptophyte algae acquire the carbon required for metabolic processes from the water in which they live. Whether carbon is actively moved across the cell membrane via a carbon concentrating mechanism, or passively through diffusion, is important for haptophyte biochemistry. The possible utilisation of carbon concentrating mechanisms also has the potential to overprint [...]

Iron oxide reactivity controls organic matter mineralization in ferruginous sediments

André Friese, Kohen Bauer, Clemens Glombitza, Luis Ordóñez, Daniel Ariztegui, Verena B. Heuer, Aurèle Vuillemin, Cynthia Henny, Sulung Nomosatryo, Rachel Simister

Published: 2020-07-10
Subjects: Biogeochemistry, Earth Sciences, Life Sciences, Physical Sciences and Mathematics

Ferruginous sediments were widespread during the Archaean and Proterozoic Eons, but our knowledge about organic matter mineralization remains mostly conceptual, as analogous modern ferruginous sediments are largely unstudied. In sediments of ferruginous Lake Towuti, Indonesia, methanogenesis dominates organic matter mineralization despite abundant reactive ferric iron phases persisting throughout [...]

Carbon fractions in the world’s dead wood

Adam R Martin, Grant M. Dimke, Mahendra Doraisami, Sean C. Thomas

Published: 2020-06-05
Subjects: Biogeochemistry, Earth Sciences, Environmental Sciences, Physical Sciences and Mathematics

Alarming increases in tree mortality due to environmental change suggest that contributions of dead wood to global carbon (C) cycles are rapidly increasing 1-3, with dead wood C flux estimates already approximating total annual anthropogenic C emissions 4. Quantifying C in dead wood critically depends on accurate estimates of dead wood C fractions (CFs) to convert dead woody biomass into C. Most [...]

Fate of intertidal microphytobenthos nitrogen under enhanced nutrient availability: Evidence for reduced nitrogen retention revealed through 15N-labeling

Philip Riekenberg, Joanne Oakes, Bradley Eyre

Published: 2020-05-26
Subjects: Biogeochemistry, Earth Sciences, Physical Sciences and Mathematics

Sediment microbial communities are an important sink for both organic and inorganic nitrogen (N), with microphytobenthos (MPB) biomass having the largest contribution to short-term N-assimilation and retention. Coastal waters are increasingly subject to anthropogenic nutrient enrichment, but the effect of this nutrient enrichment on microbial assimilation, processing, and fate of MPB-derived N [...]

Shining light on priming in euphotic sediments: Nutrient enrichment stimulates export of stored organic matter

Philip Riekenberg, Joanne Oakes, Bradley Eyre

Published: 2020-05-26
Subjects: Biogeochemistry, Earth Sciences, Life Sciences, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics

Estuarine sediments are important sites for the interception, processing and retention of organic matter, prior to its export to the coastal oceans. Stimulated microbial co-metabolism (priming) potentially increases export of refractory organic matter through increased production of hydrolytic enzymes. By using the microphytobenthos community to directly introduce a pulse of labile carbon into [...]

Preservation of Organic Carbon in Dolomitized Cambrian Stromatolites and Implications for Microbial Biosignatures in Diagenetically Replaced Carbonate Rock

Ashley Elizabeth Murphy, Scott T. Wieman, Juliane Gross, Jennifer C. Stern, Andrew Steele, Mihaela Glamoclija

Published: 2020-05-26
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Planetary Geology, Planetary Sciences

Stromatolites have been a major focus in the search for ancient microbial biosignatures, however, the organic carbon biosignatures of dolomitized stromatolites have not yet been fully characterized and correlated with their dolomitizing conditions. The lack in detailed dolomitic stromatolite studies is likely because dolomitization rarely preserves microbial morphology, which hampers the [...]

Human Health Benefits of the Minamata Convention on Mercury

Yanxu Zhang, Stephanie Dutkiewicz, Huanxin Zhang, Shiliang Wu, Long Chen, Shuxiao Wang, Ping Li, Feiyue Wang

Published: 2020-05-17
Subjects: Atmospheric Sciences, Biogeochemistry, Climate, Earth Sciences, Environmental Health and Protection, Environmental Sciences, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics

The Minamata Convention is a legally-binding international treaty aimed at reducing the anthropogenic release of mercury, a potent neurotoxin. However, its human health benefit has not been quantified on a global scale. Here we evaluate the Convention’s benefit by a coupled climate-atmosphere-land-ocean-ecosystem model and a human mercury exposure component that considers all food categories. We [...]

International disparities in open access practices of the Earth Sciences community

Olivier Pourret, David William Hedding, Dasapta Erwin Irawan, Haiyan Liu, Jonathan Tennant

Published: 2020-03-31
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Hydrology, Library and Information Science, Mineral Physics, Other Earth Sciences, Paleobiology, Paleontology, Physical Sciences and Mathematics, Sedimentology, Social and Behavioral Sciences, Soil Science, Speleology, Stratigraphy, Tectonics and Structure, Volcanology

Short communication on international disparities in open access practices of the Earth Sciences community

On the potential of preprints in geochemistry: the good, the bad and the ugly

Olivier Pourret, Dasapta Erwin Irawan, Jonathan Tennant

Published: 2020-03-21
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Library and Information Science, Physical Sciences and Mathematics, Social and Behavioral Sciences

Short communication on the use of preprint in geochemistry

Fate of adsorbed organic compounds during transformation of ferrihydrite: implications for biogenic origin of Precambrian iron formations

Stanislav Jelavic, Andrew Mitchell, Karina Krarup Sand

Published: 2020-01-30
Subjects: Biogeochemistry, Chemistry, Earth Sciences, Physical Chemistry, Physical Sciences and Mathematics

The absence of organic compounds from Precambrian iron formations (IF) challenges the hypothesis of their biogenic origin. Here we address the fate of adsorbed organic compounds during transformation from ferrihydrite to hematite. We determined the binding energy between hematite and common molecular terminations found in extracellular polymeric substances and biofilms: carboxylic, alcohol and [...]

Magnetite biomineralization in ferruginous waters and early Earth evolution

Kohen Bauer, James Byrne, Paul Kenward, Rachel Simister, Celine Michiels, Andre Friese, Aurele Vuillemin, Cynthia Henny, Sulung Nomosatryo, Jens Kallmeyer

Published: 2020-01-09
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Physical Sciences and Mathematics

Burial of large quantities of magnetite (Fe(II)Fe(III)2O4) in iron formations (IFs) likely contributed to the protracted oxidation of Earth’s surface during the Precambrian Eons. Magnetite can form through a diversity of biological and abiotic pathways and its preservation in IFs may thus be variably interpreted as the result of some combination of these processes. Such interpretations thus give [...]

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