Filtering by Subject: Geochemistry
Published: 2021-05-02
Subjects: Earth Sciences, Geochemistry
The calculation of a reliable temperature dependent dolomite solubility product constant (Ksp°−dol) has been the subject of much research over the last 70 years. This study evaluates log10(aCa2+/aMg2+) using PHREEQC (Pitzer approach) for a screened subset (n=11,480) of formation waters in the U.S. Geological Survey National Produced Waters Geochemical Database V2 (PWGD), an extensive inventory of [...]
Published: 2021-04-26
Subjects: Geochemistry, Geology
The Mongol–Okhotsk Belt is the youngest segment of the Central Asian Orogenic Belt, which is the venue of the massive juvenile crust emplacement, and it is formation and evolutions are still pending problems. This paper presents the first up-to-date U-Pb zircon ages, Hf-in-zircon isotope, geochemical and whole-rock Nd isotope data from igneous rocks of the Khangay–Khentey basin, Central Mongolia. [...]
Published: 2021-04-15
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The geochemistry of river sediments is routinely used to obtain information about geologic and environmental processes occurring upstream. For example, downstream samples are used to constrain chemical weathering and physical erosion rates, as well as the locations of mineral deposits or contaminant sources. Previous work has shown that, by assuming conservative mixing, the geochemistry of [...]
Published: 2021-04-15
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Planetary Geology
Biosignatures in the rock record limit the time available for life to start on Earth to 600-800 million years1 (4.5-3.7 Ga; Hadean-Archean). Whether the conditions for the synthesis of complex organic molecules were unique to this time or remain present today is unclear, but understanding these conditions is essential for the search of life on other planets. The outer portion of the Hadean Earth [...]
Published: 2021-04-07
Subjects: Climate, Geochemistry, Geology, Physical Sciences and Mathematics, Soil Science
Since the last glacial period, North America has experienced dramatic changes in regional climate, including the collapse of ice sheets and changes in effective precipitation. We use clumped isotopes and analysis of transient climate simulations to provide constraints on hydroclimate changes in the Pacific Northwest. The coldest soil temperatures (~10.5 ±1.°C to 14.9 ±1.2°C) occurred [...]
Published: 2021-03-17
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy
Stable carbon isotope curves are used as a precise stratigraphic tool in the Paleozoic, even though they are commonly based on shallow-water carbonate record, characterized by low stratigraphic completeness. Identification of episodes of large-scale redeposition and erosion may improve δ13Ccarb-based correlations. Here, a series of at least three episodes of high-energy onshore redeposition are [...]
Published: 2021-03-12
Subjects: Astrophysics and Astronomy, Earth Sciences, Geochemistry, Planetary Geochemistry, Planetary Sciences
Weathering of silicate rocks at a planetary surface can draw down CO2 from the atmosphere for eventual burial and long-term storage in the planetary interior. This process is thought to provide essential negative feedback to the carbonate-silicate cycle (carbon cycle) to maintain clement climates on Earth and potentially similar temperate exoplanets. We implement thermodynamics to determine [...]
Published: 2021-03-11
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy
The Trezona carbon isotope excursion is recorded on five different continents in platform carbonates deposited prior to the end-Cryogenian Marinoan glaciation (>635 Ma) and represents a change in carbon isotope values of 16-18 per mill. Based on the spatial and temporal reproducibility, the excursion previously has been interpreted as tracking the carbon isotopic composition of dissolved [...]
Published: 2021-03-04
Subjects: Atmospheric Sciences, Biogeochemistry, Chemistry, Climate, Earth Sciences, Environmental Chemistry, Environmental Public Health, Environmental Sciences, Environmental Studies, Geochemistry, Geology, Geomorphology, Hydrology, Medicine and Health Sciences, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics, Public Health, Social and Behavioral Sciences
The Salton Sea, a hypersaline lake in southern California, USA, is in crisis. A combination of mismanagement and competition between federal, state and local agencies has resulted in stalled efforts to address dropping water levels and unstable lake biogeochemistry. This in turn has led to a growing public health crisis as exposed shoreline exposes potentially toxic dust to local and regional [...]
Published: 2021-02-24
Subjects: Earth Sciences, Geochemistry, Geology, Tectonics and Structure
Forearc basins preserve the geologic record relating strictly to arc magmatism. The provenance of forearc sediment can be used to differentiate periods of crustal growth, accretion, and destruction, enhanced magmatism, advancing and retreating subduction slabs, delamination, etc. All these tectonic events systems predict differing degrees of sedimentary reworking of the older forearc units. [...]
Published: 2021-02-18
Subjects: Earth Sciences, Geochemistry, Other Earth Sciences, Physical Sciences and Mathematics, Volcanology
The flow of high-temperature and compositionally-enriched material between mantle plumes and nearby spreading centres influences up to 30% of the global mid-ocean ridge system and represents a significant, but currently unconstrained, flux of volatiles out of the mantle. Here we present new analyses of H2O, F, Cl and S in basaltic glass chips from an archetypal region of plume-ridge interaction, [...]
Published: 2021-02-10
Subjects: Geochemistry, Geology, Tectonics and Structure
Late Quaternary coral growth ages from uplifted coastal regions, such as marine terraces and associated palaeoshorelines, are an essential tool used to derive tectonic and fault controlled uplift and deformation rates, and thus contribute to seismic hazard analysis and constrain past global sea levels. Fossil coral growth ages are assessed for reliability based upon whether the δ234Ui (or [...]
Published: 2021-02-01
Subjects: Earth Sciences, Environmental Sciences, Geochemistry, Geology, Numerical Analysis and Scientific Computing, Statistics and Probability, Volcanology
Minerals exhibit zoning patterns that can be related to changes in the environment in which they grew. Using statistical methods that have been designed to segment optical images, we have developed a procedure to segment zonation within minerals and correlate these zones between multiple crystals using elemental maps. This allows us to quantify the complexity and variability of chemical zoning [...]
Published: 2021-02-01
Subjects: Biogeochemistry, Earth Sciences, Environmental Indicators and Impact Assessment, Environmental Monitoring, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Multivariate Analysis, Oil, Gas, and Energy, Other Earth Sciences, Paleobiology, Paleontology, Sedimentology
Ordination is the name given to a group of methods used to analyze multiple variables without preceding hypotheses. Over the last few decades the use of these methods in Earth science in general, and notably in analyses of sedimentary sources, has dramatically increased. However, with limited resources oriented towards Earth scientists on the topic, the application of ordination analysis is at [...]
Published: 2021-02-01
Subjects: Earth Sciences, Geochemistry, Geology, Stratigraphy, Volcanology
Establishing a quantitative link between magmatic processes occurring at depth and volcanic eruption dynamics is essential to forecast the future behaviour of volcanoes, and to correctly interpret monitoring signals at active centres. Chemical zoning in minerals, which captures successive events or states within a magmatic system, can be exploited for such a purpose. However, to develop a [...]