Generation of Reproducible Model Freshwater Particulate Matter Analogues to Study the Interaction with Particulate Contaminants.

This is a Preprint and has not been peer reviewed. The published version of this Preprint is available: https://doi.org/10.1016/j.watres.2022.119385. This is version 1 of this Preprint.

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Authors

Helene Walch, Antonia Praetorius, Frank von der Kammer, Thilo Hofmann

Abstract

Aquatic fate models and risk assessment require experimental information on the potential of contaminants to interact with riverine suspended particulate matter (SPM). While for dissolved contaminants partition or sorption coefficients are used, the underlying assumption of chemical equilibrium is invalid for particulate contaminants, such as engineered nanomaterials, incidental nanoparticles, micro- or nanoplastics. Their interactions with SPM are governed by physicochemical forces between contaminant-particle and SPM surfaces. The availability of a standard SPM material is thus highly relevant for the development of reproducible test systems to evaluate the fate of particulate contaminants in aquatic systems. Finding suitable SPM analogues, however, is challenging considering the complex composition of natural SPM, which features floc-like structures comprising minerals and organic components from the molecular to the microorganism level. Complex composition comes with a heterogeneity in physicochemical surface properties, that cannot be neglected. We developed a procedure to generate SPM analogue flocs from components selected to represent the most abundant and crucial constituents of natural riverine SPM, and the process-relevant SPM surface characteristics regarding interactions with particulate contaminants. Four components, i.e., illite, hematite, quartz and tryptophan, combined at environmentally realistic mass-ratios, were associated to complex flocs. Flocculation was reproducible regarding floc size and fractal dimension, and multiple tests on floc resilience towards physical impacts (agitation, sedimentation-storage-resuspension, dilution) and hydrochemical changes (pH, electrolytes, dissolved organic matter concentration) confirmed their robustness. These reproducible, ready-to-use SPM analogue flocs will strongly support future research on emerging particulate contaminants.

DOI

https://doi.org/10.31223/X5ZW7Q

Subjects

Environmental Chemistry, Environmental Health and Protection, Environmental Sciences, Fresh Water Studies

Keywords

suspended particulate matterenvironmental risk assessment, fate, heteroagglomeration, nanoparticles, microplastics, suspended particulate matter, environmental risk assessment, fate, heteroaggregation, nanoparticles, microplastics

Dates

Published: 2022-08-31 02:29

License

CC BY Attribution 4.0 International

Additional Metadata

Conflict of interest statement:
None