Ultramafic rock carbonation: Constraints from listvenite core BT1B, Oman Drilling Project

This is a Preprint and has not been peer reviewed. The published version of this Preprint is available: https://doi.org/10.1029/2019JB019060.

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Authors

Andreas Beinlich , Oliver Plümper, Esmée Boter, Inigo A. Müller, Fatma Kourim, Martin Ziegler , Yumiko Harigane, Romain Lafay, Peter B. Kelemen

Abstract

The occurrence of the quartz–carbonate alteration assemblage (listvenite) in ophiolites indicates that ultramafic rock represents an effective sink for dissolved CO2. However, the majority of earlier studies of ultramafic rock carbonation had to rely on the surface exposure of reaction textures and field relationships. Here we present the first observations on ultramafic rock alteration obtained from the 300 m deep BT1B drill hole, ICDP Oman Drilling Project, allowing for a continuous and high-resolution investigation. Hole BT1B recovered continuous drill core intersecting surface alluvium, 200 meters of altered ultramafic rock comprising mainly listvenite and minor serpentinite bands at 90 m and 180 m depth, and 100 meters of the underlying metamorphic sole. Textural evidence suggests that the carbonation of fully serpentinized harzburgite commenced by non-equilibrium growth of spheroidal carbonate characterized by sectorial zoning resulting from radially oriented low-angle boundaries. In the serpentinite, carbonate spheroids are composed of alternating magnesite cores and dolomite rims, whereas texturally similar carbonate in the listvenite is composed of Fe-rich magnesite cores and Ca-Fe-rich magnesite rims. The distinct compositions and mineral inclusions indicate that the carbonation extent was controlled by fluid accessibility resulting in the simultaneous formation of limited carbonate in the serpentinite bands and complete carbonation in the listvenite parts of BT1B. The presence of euhedral magnesite overgrowing spheroidal carbonate in the listvenite suggests near-equilibrium conditions during the final stage of carbonation. The carbonate clumped isotope thermometry constrains carbonate crystallization between 50°C and 250°C, implying repeated infiltration of reactive fluids during ophiolite uplift and cooling.

DOI

https://doi.org/10.31223/osf.io/n6swu

Subjects

Earth Sciences, Geochemistry, Geology, Mineral Physics, Other Earth Sciences, Physical Sciences and Mathematics

Keywords

Carbonation, Oman ophiolite, Clumped isotope, Fluid-rock interaction

Dates

Published: 2019-11-14 16:17

Last Updated: 2020-04-15 23:07

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License

CC BY Attribution 4.0 International

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