Preprints
Filtering by Subject: Geochemistry
Distributions of geohopanoids in peat: implications for the use of hopanoid-based proxies in natural archives
Published: 2018-02-04
Subjects: Biogeochemistry, Chemistry, Earth Sciences, Environmental Sciences, Geochemistry, Other Physical Sciences and Mathematics, Physical Sciences and Mathematics
Hopanoids are pentacyclic triterpenoids produced by a wide range of bacteria. Within modern settings, hopanoids mostly occur in the biological 17β,21β(H) configuration. However, in some modern peatlands, the C31 hopane is present as the thermally-mature 17α,21β(H) stereoisomer. This has traditionally been ascribed to isomerisation at the C-17 position catalysed by the acidic environment. However, [...]
Detecting orogenic wedge state and the rise of the External Alps by detrital thermochronology
Published: 2018-01-26
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Tectonics and Structure
Critical taper theory permits the modelling of an orogenic wedge as a single mechanical entity. However, although shallow-crustal orogens dominated by brittle failure have been successfully modelled using critical taper, this remains controversial for major, ductile-failure-dominated orogens. In critical taper models, the steepness of the basal and upper orogenic surfaces defines the critical [...]
Relict topography within the Hangay Mountains in central Mongolia: Quantifying long-term exhumation and relief change in an old landscape
Published: 2018-01-14
Subjects: Earth Sciences, Geochemistry, Geology, Geomorphology, Physical Sciences and Mathematics, Tectonics and Structure
The Hangay Mountains are a high-elevation, low-relief landscape within the greater Mongolian Plateau of central Asia. New bedrock apatite (U-Th)/He single-grain ages from the Hangay span ~70 to 200 Ma, with a mean of 122.7 ± 24.0 Ma (2σ). Detrital apatite samples from the Selenga and Orkhon Rivers, north of the mountains, yield dominant (U-Th)/He age populations of ~115 to 130 Ma, as well as an [...]
Climate-driven unsteady denudation and sediment flux in a high-relief unglaciated catchment-fan using 26Al and 10Be: Panamint Valley, California
Published: 2018-01-13
Subjects: Earth Sciences, Geochemistry, Geology, Geomorphology, Physical Sciences and Mathematics, Sedimentology
Environmental changes within erosional catchments of sediment routing systems are predicted to modulate sediment transfer dynamics. However, empirical and numerical models that predict such phenomena are difficult to test in natural systems over multi-millennial timescales. Tectonic boundary conditions and climate history in the Panamint Range, California, are relatively well-constrained by [...]
Introduction to Geochronology
Published: 2017-12-29
Subjects: Cosmochemistry, Earth Sciences, Geochemistry, Physical Sciences and Mathematics
These lecture notes cover the first half of an Isotope Geology module at University College London that deals with the geochronological aspects of the subject. The notes introduce the basic principles of radioactive decay, mass spectrometry and isotope dilution before discussing the most common geochronometers in use today, including radiocarbon, Rb-Sr, Sm-Nd, U-Pb, Pb-Pb, K-Ar, Ar-Ar, U-Th-He, [...]
Temperatures recorded by cosmogenic noble gases since the last glacial maximum in the Maritime Alps
Published: 2017-11-24
Subjects: Earth Sciences, Geochemistry, Geomorphology, Glaciology, Other Earth Sciences, Physical Sciences and Mathematics
While proxy records have been used to reconstruct late Quaternary climate parameters throughout the European Alps, our knowledge of deglacial climate conditions in the Maritime Alps is limited. Here, we report temperatures recorded by a new and independent geochemical technique—cosmogenic noble gas paleothermometry—in the Maritime Alps since the last glacial maximum. We measured cosmogenic 3He in [...]
The INTAV intercomparison of electron-beam microanalysis of glass by tephrochronology laboratories, results and recommendation
Published: 2017-11-23
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The INternational focus group on Tephrochronology And Volcanism (INTAV) of the International Union for Quaternary Research (INQUA) has conducted an intercomparison of tephrochronology laboratories with electron-beam microanalytical data on volcanic glasses submitted from 27 instruments at 24 institutions in 9 countries. This assessment includes most active tephrochronology laboratories and [...]
Quantifying closed-basin lake temperature and hydrology by inversion of oxygen isotope and trace element paleoclimate records
Published: 2017-11-08
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Lake systems are important paleoclimate archives that preserve ecosystem and hydrologic responses to critical periods in Earth history, such as carbon cycle perturbations and glacial-interglacial cycles. Geochemical measurements of biogenic carbonate (for example, δ18O, δ13C, 87Sr/86Sr, [Li], [U], [Sr], and [Mg]) are indicators of hydrologic variability in lake systems throughout the geologic [...]
Constraints on the numerical age of the Paleocene‐Eocene boundary
Published: 2017-11-05
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Stratigraphy
Here we present combined radioisotopic dating (U-Pb zircon) and cyclostratigraphic analysis of the carbon isotope excursion at the Paleocene-Eocene (P-E) boundary in Spitsbergen to determine the numerical age of the boundary. Incorporating the total uncertainty from both radioisotopic and cyclostratigraphic data sets gives an age ranging from 55.728 to 55.964 Ma, within error of a recently [...]
UPb LA-(MC)-ICP-MS dating of rutile: New reference materials and applications to sedimentary provenance
Published: 2017-11-05
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
In response to the general lack of sufficiently abundant and high quality rutile UPb reference materials for in situ geochronology, we have characterised two new potential rutile ~ 1.8 Ga reference materials (Sugluk-4 and PCA-S207) from granulite facies belts of the Canadian Shield, namely the northern Cape Smith Belt of Quebec and the Snowbird Tectonic Zone (Sasatchewan). Characterisation [...]
Multiple Palaeoproterozoic carbon burial episodes and excursions
Published: 2017-11-05
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Stratigraphy
Organic-rich rocks (averaging 2–5% total organic carbon) and positive carbonate-carbon isotope excursions ( ‰ δC13>+5‰ and locally much higher, i.e. the Lomagundi-Jatuli Event) are hallmark features of Palaeoproterozoic successions and are assumed to archive a global event of unique environmental conditions following the c. 2.3 Ga Great Oxidation Event. Here we combine new and published [...]
Dating the termination of the Palaeoproterozoic Lomagundi-Jatuli carbon isotopic event in the North Transfennoscandian Greenstone Belt
Published: 2017-11-05
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Stratigraphy
Existing radio-isotopic age constraints indicate that the global Palaeoproterozoic Lomagundi-Jatuli large, positive carbonate carbon isotopic excursion, with δ13C values >+5‰, occurred between 2.2 and 2.06 Ga. In the North Transfennoscandian Greenstone Belt of the Kola Peninsula, NW Russia, northern Norway and Finland, the Lomagundi-Jatuli Event is recorded in the carbonate rocks of the Umba [...]
A users guide to Neoproterozoic geochronology
Published: 2017-11-05
Subjects: Earth Sciences, Geochemistry, Geology, Paleontology, Physical Sciences and Mathematics, Stratigraphy
Geochronology is essential for understanding Neoproterozoic Earth history. Here we review the types of rocks and minerals that are used to date geologic events and the analytical protocols for the different radio-isotopic decay systems employed. We discuss the limitations and potential of these methodologies for dating Neoproterozoic stratigraphy, highlighting the major sources and magnitudes of [...]
Isotopic composition (238U/235U) of some commonly used uranium reference materials
Published: 2017-11-05
Subjects: Chemistry, Cosmochemistry, Earth Sciences, Geochemistry, Inorganic Chemistry, Physical Sciences and Mathematics
We have determined 238U/235U ratios for a suite of commonly used natural (CRM 112a, SRM 950a, and HU-1) and synthetic (IRMM 184 and CRM U500) uranium reference materials by thermal ionisation mass-spectrometry (TIMS) using the IRMM 3636 233U–236U double spike to accurately correct for mass fractionation. Total uncertainty on the 238U/235U determinations is estimated to be <0.02% (2σ). These [...]
238U/235U Systematics in Terrestrial Uranium-Bearing Minerals
Published: 2017-11-05
Subjects: Chemistry, Cosmochemistry, Earth Sciences, Geochemistry, Inorganic Chemistry, Physical Sciences and Mathematics
The present-day 238U/235U ratio has fundamental implications for uranium-lead geochronology and cosmochronology. A value of 137.88 has previously been considered invariant and has been used without uncertainty to calculate terrestrial mineral ages. We report high-precision 238U/235U measurements for a suite of uranium-bearing minerals from 58 samples representing a diverse range of lithologies. [...]