Preprints
Filtering by Subject: Biogeochemistry
Dark carbon fixation contributes to sedimentary organic carbon in the Arabian Sea oxygen minimum zone
Published: 2019-05-18
Subjects: Biogeochemistry, Earth Sciences, Environmental Microbiology and Microbial Ecology Life Sciences, Life Sciences, Microbiology, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics
In response to rising CO2 concentrations and increasing global sea surface temperatures, oxygen minimum zones (OMZ), or “dead zones”, are expected to expand. OMZs are fueled by high primary productivity, resulting in enhanced biological oxygen demand at depth, subsequent oxygen depletion, and attenuation of remineralization. This results in the deposition of organic carbon-rich sediments. Carbon [...]
A first look at dissolved Ge isotopes in marine sediments
Published: 2019-04-28
Subjects: Biogeochemistry, Earth Sciences, Physical Sciences and Mathematics
The removal of chemical species from seawater during the precipitation of authigenic minerals is difficult to constrain but may play a major role in the global biogeochemical cycles of some elements, including silicon (Si) and germanium (Ge). Here, we present Ge/Si, δ74Ge, and supporting chemical data of pore waters and core incubations at three continental margin sites in California and the Gulf [...]
Terrestrial environmental change across the onset of the PETM and the associated impact on biomarker proxies: a cautionary tale
Published: 2019-04-28
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics
The Paleocene-Eocene Thermal Maximum (PETM; ~ 56 million years ago (Ma) is the most severe carbon cycle perturbation event of the Cenozoic. Although the PETM is associated with warming in both the surface (~up to 8°C) and deep ocean (~up to 5°C), there are relatively few terrestrial temperature estimates from the onset of this interval. The associated response of the hydrological cycle during the [...]
A long-term, high-latitude record of Eocene hydrological change in the Greenland region
Published: 2019-04-26
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics
A range of proxy approaches have been used to reconstruct short-term changes to Earth’s hydrological cycle during the early Eocene hyperthermals. However, little is known about the response of Earth’s hydrological and biogeochemical systems to long-term Cenozoic cooling, which began following the Early Eocene Climatic Optimum (53.3 – 49.4 million years ago; Ma). Here, we use the molecular [...]
Separating isotopic impacts of karst and in-cave processes from climate variability using an integrated speleothem isotope-enabled forward model
Published: 2019-03-12
Subjects: Biogeochemistry, Earth Sciences, Hydrology, Physical Sciences and Mathematics, Speleology
Speleothem δ18O values are commonly used to infer past climate variability. However, both non-linear karst hydrological processes and in-cave disequilibrium isotope fractionation are recognised and hinder the interpretation of δ18O values. In recent years, proxy system models (PSMs) have emerged to quantitatively assess the confounding effects of these processes. This study presents the first [...]
Human-induced fire regime shifts during 19th century industrialization: a robust fire regime reconstruction using northern Polish lake sediments
Published: 2019-02-22
Subjects: Biogeochemistry, Earth Sciences, Environmental Sciences, Other Earth Sciences, Physical Sciences and Mathematics
Fire regime shifts are driven by climate and natural vegetation changes, but can be strongly affected by human land management. Yet, it is poorly known how exactly humans have influenced fire regimes prior to active wildfire suppression. Among the last 250 years, the human contribution to the global increase in fire occurrence during the mid-19th century is especially unclear, as data sources are [...]
Long Range Correlation in Redox Potential Fluctuations Signals Energetic Efficiency of Bacterial Fe(II) Oxidation
Published: 2019-02-21
Subjects: Biogeochemistry, Earth Sciences, Environmental Sciences, Physical Sciences and Mathematics
Differentiating biotic and abiotic processes in nature remains a persistent challenge, specifically in evaluating microbial contributions to geochemical processes through time. Building on previous work reporting that biologically-influenced systems exhibit stronger long-range correlation than abiotic systems, this study evaluated the relationship between long-range correlation of redox [...]
The organic component of the earliest sulfur cycling
Published: 2019-01-16
Subjects: Biogeochemistry, Earth Sciences, Physical Sciences and Mathematics
The chemistry of the Early Earth is widely inferred from the elemental and isotopic compositions of sulfidic sedimentary rocks, which are presumed to have formed globally through the reduction of seawater sulfate or locally from hydrothermally supplied sulfide. Here we argue that, in the sulfate-poor ferruginous oceans of the Archean eon, organic sulfur must have played an important and [...]
Critical Review of Polyphosphate and Polyphosphate Accumulating Organisms for Agricultural Water Quality Management
Published: 2018-12-03
Subjects: Agriculture, Biogeochemistry, Earth Sciences, Environmental Microbiology and Microbial Ecology Life Sciences, Environmental Sciences, Life Sciences, Microbiology, Natural Resources Management and Policy, Physical Sciences and Mathematics, Soil Science, Water Resource Management
Despite ongoing management efforts, phosphorus (P) loading from agricultural landscapes continues to impair water quality. Wastewater treatment research has enhanced our knowledge of microbial mechanisms influencing P cycling, especially regarding microbes known as polyphosphate accumulating organisms (PAOs) that store P as polyphosphate (polyP) under oxic conditions and release P under anoxic [...]
Geomorphology and Climate Interact to Control Organic Carbon Stock and Age in Mountain River Valley Bottoms
Published: 2018-10-08
Subjects: Biogeochemistry, Earth Sciences, Geomorphology, Physical Sciences and Mathematics
Organic carbon (OC) in valley bottom downed wood and soil that cycles over short to moderate timescales represents a large, dynamic, and poorly quantified pool of carbon whose distribution and residence time affects global climate. We compare four disparate mountain river basins to show that mountain river valley bottoms store substantial estimated OC stocks in floodplain soil and downed wood. [...]
Grand Challenges (and Great Opportunities) in Sedimentology, Stratigraphy, and Diagenesis Research
Published: 2018-09-23
Subjects: Biogeochemistry, Earth Sciences, Geomorphology, Physical Sciences and Mathematics, Sedimentology, Stratigraphy
Technological advances make these exciting times for geoscientists studying Earth surface processes, their depositional products, and interactions with the biosphere, hydrosphere, atmosphere, and lithosphere; from monitoring contemporary sediment transport processes to interpretation of sedimentary archives that record ancient environmental changes. We set out three research challenges: 1) [...]
Quantifying the Fate of Wastewater Nitrogen Discharged to a Canadian River
Published: 2018-06-21
Subjects: Biogeochemistry, Earth Sciences, Environmental Indicators and Impact Assessment, Environmental Monitoring, Environmental Sciences, Life Sciences, Physical Sciences and Mathematics, Systems Biology, Water Resource Management
Addition of nutrients, such as nitrogen, can degrade water quality in lakes, rivers, and estuaries. To predict the fate of nutrient inputs, an understanding of the biogeochemical cycling of nutrients is needed. We develop and employ a novel, parsimonious, process-based model of nitrogen concentrations and stable isotopes that quantifies the competing processes of volatilization, uptake, [...]
Pervasive iron limitation at subsurface chlorophyll maxima of the California Current
Published: 2018-05-24
Subjects: Biogeochemistry, Earth Sciences, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics
Subsurface chlorophyll maximum layers (SCMLs) are nearly ubiquitous in stratified water columns and exist at horizontal scales ranging from the submesoscale to the extent of oligotrophic gyres. These layers of heightened chlorophyll and/or phytoplankton concentrations are generally thought to be a consequence of a balance between light energy from above and a limiting nutrient flux from below, [...]
Towards a global interpretation of dual nitrate isotopes in natural water
Published: 2018-05-22
Subjects: Biogeochemistry, Earth Sciences, Environmental Indicators and Impact Assessment, Environmental Sciences, Physical Sciences and Mathematics, Water Resource Management
Modern anthropogenic activities have significantly increased nitrate (NO3-) concentrations in surface waters. Stable isotopes (δ15N and δ18O) in NO3- offer a tool to deconvolute some of the human-made changes in the nitrogen cycle. They are often graphically illustrated on a template designed to identify different sources of NO3- and denitrification. In the two decades since this template was [...]
Metabolite cycling indicated by long-range correlation in a sediment bioreactor mixed microbial community
Published: 2018-05-16
Subjects: Biogeochemistry, Earth Sciences, Environmental Sciences, Geochemistry, Physical Sciences and Mathematics
Geophysical surveys add value to biogeochemical studies because of their ability to characterize systems remotely, and their precise time resolution. One limitation, however, is their lack of biogeochemical process specificity. Here, electrochemical time series from an oxic-anoxic cyclical bioreactor experiment were reanalyzed with detrended fluctuation analysis (DFA) to distinguish dominant [...]