Felix Boschetty, David Ferguson, Joaquín Cortés, Eduardo Morgado, Susanna Ebmeier, Daniel Morgan, Jorge Romero, Carolina Silva Parejas

A key method to investigate magma dynamics is the analysis of the crystal cargoes carried by erupted magmas. These cargoes may comprise crystals that crystallize in different parts of the magmatic system (throughout the crust) and/or different times. While an individual eruption likely provides a partial view of the sub-volcanic plumbing system, compiling data from multiple eruptions builds a picture of the whole magmatic system. In this study we use machine learning techniques to analyze a large (>2000) compilation of mineral compositions from a highly active arc volcano: Villarrica, Chile. Villarrica's post-glacial eruptive activity (14 ka–present) displays large variation in eruptive style (mafic ignimbrites to Hawaiian effusive eruptions) yet its eruptive products have a near constant basalt-basaltic andesite bulk-rock composition. What, therefore, is driving explosive eruptions at Villarrica and can differences in storage dynamics be related to eruptive style? We used hierarchical cluster analysis to detect previously undetected structure in olivine, plagioclase and clinopyroxene compositions, revealing the presence of compositionally distinct clusters. Using rhyolite-MELTS thermodynamic modeling we related these clusters to intensive magmatic variables: temperature, pressure, water content and oxygen fugacity. Our results provide evidence for the existence of multiple discrete (spatial and temporal) magma reservoirs beneath Villarrica where melts differentiate and mix with incoming more primitive magma. The compositional diversity of an erupted crystal cargo strongly correlates with eruptive intensity, and we postulate that mixing between primitive and differentiated magma drives explosive activity at Villarrica.