Preprints
Filtering by Subject: Geochemistry
The applicability of G-BASE stream sediment geochemistry as a combined geological mapping, and prospective exploration tool for As-Co-Cu-Ni mineralisation across Cumbria, UK.
Published: 2023-01-18
Subjects: Earth Sciences, Geochemistry, Geology, Multivariate Analysis, Physical Sciences and Mathematics, Statistics and Probability
Stream sediment geochemistry is a useful tool to analyse the geochemistry of the local geology within the source catchment area. This has significant applicability within the field of mineral exploration where understanding regional lithological geochemistry is needed, facilitating the identification of critical metal deposits. Successful identification of these deposits is essential to help [...]
A multi-siderophile element connection between volcanic hotspots and Earth’s core
Published: 2023-01-18
Subjects: Geochemistry
The existence of resolvable 182W/184W deficits in modern ocean island basalts (OIB) relative to the bulk silicate Earth has raised questions about the relationship of these rocks to Earth’s core. However, because the core is expected to host high abundances of highly siderophile elements (HSE), it would be expected that such heterogeneity is accompanied by correlating variability in HSE [...]
Diffusion of halogens (F, Cl, Br, I) in silicic melt
Published: 2023-01-10
Subjects: Earth Sciences, Geochemistry, Volcanology
Chemical diffusion of the halogens F, Cl, Br, and I in silica-rich natural melts was experimentally investigated by the diffusion couple technique. Experiments were conducted under anhydrous conditions at atmospheric pressure and hydrous conditions (~1.5 wt.% H2O) at 160 MPa, over a temperature range of 750–1000 °C and 1000–1200 °C, respectively. Quenched trachytic melt samples were analyzed [...]
Are marl-limestone alternations mainly driven by CaCO3 variations at the astronomical timescale? New insights from extraterrestrial 3He
Published: 2023-01-07
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy
Marl-limestone alternations are rhythmical inter-bedded deposits that commonly occur in many sedimentological environments. It is quite well established that these lithological variations originate from astronomically-driven climatic variations paced by the Milankovitch cycles of main periods 19, 23, 41, 100 and 405 ka. However, the sedimentological mechanisms involved are not clear: some models [...]
Tracing timing of growth in cultured mollusks using strontium spiking
Published: 2022-12-23
Subjects: Aquaculture and Fisheries Life Sciences, Biogeochemistry, Geochemistry, Paleontology
Growth experiments present a powerful tool for determining the effect of environmental parameters on growth and carbonate composition in biogenic calcifiers. For successful proxy calibration and biomineralization studies, it is vital to exactly identify volumes of carbonate precipitated at precise intervals during the experiment. Here, we investigate the use of strontium labelling in mollusk [...]
Oxidation Rates and Redox Stabilization of Ferrous Iron in Trioctahedral Smectites
Published: 2022-12-16
Subjects: Biogeochemistry, Geochemistry, Other Earth Sciences, Planetary Biogeochemistry, Planetary Geochemistry
Iron(II)-bearing trioctahedral smectites (saponites) form during anoxic alteration of basaltic rock. They are predicted to have been widespread on the early Earth and are observed in the oceanic subsurface today. Smectite structures, including the occupancy of sites in the octahedral sheet, affect iron redox behavior but the rates and products of trioctahedral smectite oxidation have been largely [...]
Barometers behaving badly II: A critical evaluation of Cpx-only and Cpx-Liq thermobarometry in variably-hydrous arc magmas
Published: 2022-12-14
Subjects: Earth Sciences, Geochemistry, Geology, Volcanology
The chemistry of erupted clinopyroxene crystals (±equilibrium liquids) have been widely used to deduce the pressures and temperatures of magma storage in volcanic arcs. However, the large number of different equations parametrizing the relationship between mineral and melt compositions and intensive variables such as pressure and temperature yield vastly different results, with [...]
Barometers behaving badly: Assessing the influence of analytical and experimental uncertainty on clinopyroxene thermobarometry calculations at crustal conditions
Published: 2022-11-30
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics, Volcanology
The composition of clinopyroxene and Clinopyroxene-Liquid (Cpx-Liq) pairs are frequently used to calculate crystallization/equilibration pressures in igneous systems. While canonical uncertainties are often assigned to calculated pressures based on fits to calibration or test datasets, the sources of these uncertainties (and thus ways to reduce them) have not been rigorously assessed. We show [...]
Lithospheric structure and melting processes in southeast Australia: new constraints from joint probabilistic inversions of 3D magnetotelluric and seismic data
Published: 2022-11-18
Subjects: Geochemistry, Geophysics and Seismology, Volcanology
The thermochemical structure of the lithosphere exerts control on melting mechanisms in the mantle as well as the location of volcanism and ore deposits. Imaging the complex interactions between the lithosphere and asthenospheric mantle requires the joint inversion of multiple data sets and their uncertainties. In particular, the combination of seismic velocity and electrical conductivity with [...]
Community recommendations for geochemical data, services and analytical capabilities in the 21st century
Published: 2022-11-17
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry
The majority of geochemical and cosmochemical research is based upon observations and, in particular, upon the acquisition, processing and interpretation of analytical data from physical samples. The exponential increase in volumes and rates of data acquisition over the last century, combined with advances in instruments, analytical methods and an increasing variety of data types analysed, has [...]
PREPRINT: A global platform solution for Big Data in low-temperature thermochronology
Published: 2022-11-12
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Low-temperature thermochronology is a powerful tool for constraining the thermal evolution of geological materials at temperatures (< ~300 °C) common in the upper crust in relation to geodynamics, continental crustal evolution, landscape evolution, and natural resource formation and preservation. However, complexities inherent to these analytical techniques can make interpreting the significance [...]
The missing carbon budget puzzle piece: shallow-water hydrothermal vents contribution to global CO2 fluxes
Published: 2022-11-08
Subjects: Earth Sciences, Geochemistry, Geology, Planetary Biogeochemistry, Volcanology
The release of CO2 gases from volcanoes and their secondary geothermal manifestations are an important contributor to the global carbon budget. While degassing from mid ocean ridges is relatively well-constrained, the contribution of shallow submarine volcanic degassing to the atmosphere is less clear. Shallow-water hydrothermal vents are common seafloor features present at depths shallower than [...]
Oceanic redox conditions during the terminal Cambrian extinction event
Published: 2022-11-04
Subjects: Geochemistry
Marine animal diversity during the late Cambrian was reduced by a series of extinctions that have generally been attributed to oceanic anoxic events associated with positive carbon isotope excursions. Here we present carbon and uranium isotope ratios (δ13C and δ238U values) as proxies for global carbon cycle and oceanic redox conditions, respectively, from carbonate rocks of the Wa’ergang [...]
Short Communication: The Wasserstein distance as a dissimilarity metric for comparing detrital age spectra, and other geological distributions
Published: 2022-10-26
Subjects: Earth Sciences, Environmental Sciences, Geochemistry, Geology, Geomorphology, Stratigraphy, Tectonics and Structure
Distributional data such as detrital age populations or grain size distributions are common in the geological sciences. As analytical techniques become more sophisticated, increasingly large amounts of distributional data are being gathered. These advances require quantitative and objective methods, such as multidimensional scaling (MDS), to analyse large numbers of samples. Crucial to such [...]
Experimental comparisons of carbonate-associated sulfate extraction methods
Published: 2022-10-26
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics
Carbonate-associated sulfate (CAS) refers to trace amounts of sulfate incorporated into carbonate minerals during precipitation. CAS has been the most commonly used approach to recover the paleo-seawater sulfate sulfur isotope composition (δ34Ssw) as carbonate rocks are more common and occur in less restricted marine environments than alternative sulfate-bearing minerals (such as gypsum and [...]