Preprints
Filtering by Subject: Geochemistry
Paleoclimate controls on lithium enrichment in Great Basin Pliocene-Pleistocene lacustrine clays
Published: 2022-05-29
Subjects: Climate, Earth Sciences, Environmental Sciences, Geochemistry, Geology, Natural Resources and Conservation, Other Environmental Sciences, Sedimentology
Terminal lakes are important archives of continental hydroclimate and in some cases contain important economic resources. Here, we present an ∼2.9 m.y. lacustrine carbonate carbon and oxygen stable isotope record from a Great Basin continental drill core. We paired these measurements with bulk lithium concentrations to reveal a relationship between past climate and lithium enrichment in [...]
A very unconventional hydrocarbon play: the Mesoproterozoic Velkerri Formation of Northern Australia
Published: 2022-05-16
Subjects: Geochemistry, Geology, Sedimentology, Stratigraphy, Tectonics and Structure
The ca. 1.5–1.3 Ga Roper Group of the greater McArthur Basin is a component of one of the most extensive Precambrian hydrocarbon-bearing basins preserved in the geological record, recently assessed as containing 429 million barrels of oil and eight trillion cubic feet of gas (in place). It was deposited in an intra-cratonic sea, referred to here as the McArthur-Yanliao Gulf. The Velkerri [...]
Quantifying excess heavy metal concentrations in drainage basins using conservative mixing models
Published: 2022-05-13
Subjects: Earth Sciences, Environmental Sciences, Geochemistry, Geomorphology, Physical Sciences and Mathematics, Sustainability, Water Resource Management
High concentrations of heavy metals and other pollutants in river sediments can have detrimental effects on the ecosystem and humans. The composition of river sediments throughout drainage basins therefore provides important information for environmental monitoring. An obvious first step for using river sediment compositions for monitoring is to quantify natural baseline concentrations. Once [...]
The CREp 36Cl exposure age calculator: development version “dev”
Published: 2022-05-04
Subjects: Geochemistry, Geology, Geomorphology, Glaciology, Sedimentology, Tectonics and Structure, Volcanology
Chlorine-36 (36Cl) is currently the only in situ cosmogenic nuclide applicable in carbonates, Ca- and K-rich feldspars and aphyric silicate rocks. Because the production reactions of 36Cl are more numerous and complex than those of other cosmogenic nuclides (e.g. 10Be, 3He), comprehensive and user-friendly calculators are essential for routine application of 36Cl to Earth surface research [...]
Radiogenic isotope: not just about words
Published: 2022-04-29
Subjects: Earth Sciences, Geochemistry
This viewpoint is a short comment on gender issues with isotope terminology. The terms "parent"/"daughter" should be avoided in favor of the more descriptive "precursor ion" and "product ion" terms.
Expansion and intensification of the North American Monsoon during the Pliocene
Published: 2022-04-14
Subjects: Climate, Earth Sciences, Geochemistry, Oceanography and Atmospheric Sciences and Meteorology
Southwestern North America, like many subtropical regions, is predicted to become drier in response to anthropogenic warming. However, during the Pliocene, when carbon dioxide was above pre-industrial levels, multiple lines of evidence suggest that southwestern North America was much wetter. While existing explanations for a wet Pliocene invoke increases in winter rain, recent modeling studies [...]
Late Glacial and Holocene Palaeolake History of the Última Esperanza Region of Southern Patagonia
Published: 2022-03-29
Subjects: Earth Sciences, Geochemistry, Geology, Geomorphology, Glaciology, Hydrology, Paleobiology, Physical Sciences and Mathematics, Sedimentology, Stratigraphy, Volcanology
We undertook multiproxy analyses on two sediment cores from Lago Pato, a small lake basin at 51°S topographically separated from Lago del Toro in Torres del Paine (TdP), to provide insights into glacier dynamics and lake level change in the TdP and Última Esperanza region over the last ~30,000 cal a BP (30 ka). Lago Pato is situated in a region overridden by the Southern Patagonian Icefield [...]
Geochronology and formal stratigraphy of the Sturtian Glaciation in the Adelaide Superbasin
Published: 2022-03-24
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy
The glaciogenic nature of the Yudnamutana Subgroup was first recognized over a century ago, and its global significance was recognized shortly after, with the eventual postulation of a global Sturtian Glaciation and Snowball Earth theory. Much debate on the origin and timing of these rocks, locally and globally, has ensued in the years since. A significant corpus of research on the lithology, [...]
Mid- to Late Neoproterozoic Development and Provenance of the Adelaide Superbasin
Published: 2022-03-22
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy, Tectonics and Structure
Late Tonian sequences of the Adelaide Superbasin were witness to the birth of the proto-Pacific Ocean during the breakup of Rodinia. Understanding the sedimentology and provenance of these rocks from across the basin is key to understanding their deposition over c. 70 million years, the local palaeogeography, and leads to a better understanding of the early development of the proto-Pacific Ocean. [...]
Abrupt shift to El Niño-like mean state conditions in the tropical Pacific during the Little Ice Age
Published: 2022-03-11
Subjects: Climate, Earth Sciences, Geochemistry, Hydrology
The mean state of the tropical Pacific ocean-atmosphere climate, in particular its east-west asymmetry, has profound consequences for regional climates and for the El Niño/ Southern Oscillation variability. Here we present a new high-resolution paleohydrological record using the stable-hydrogen-isotopic composition of terrestrial-lipid biomarkers (δDwax) from a 1,400-year-old lake sedimentary [...]
High-resolution Ge-Si-Fe, Cr isotope and Th-U data for the Neoarchean Temagami BIF, Canada, suggest primary origin of BIF bands and oxidative terrestrial weathering 2.7 Ga ago
Published: 2022-03-01
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
ABSTRACT Unique deposits that formed in the Precambrian oceans are the Banded Iron-Formations (BIFs) which are chemical sediments comprised of alternating layers of iron- and silica-dominated precipitates. The origin of this enigmatic banding is still debated, with most favoring a primary sedimentary and a few others arguing for a secondary diagenetic origin. We here used a high-resolution [...]
Freshwater Suspended Particulate Matter – Key Components and Processes in Floc Formation and Dynamics.
Published: 2022-02-18
Subjects: Biogeochemistry, Environmental Chemistry, Environmental Microbiology and Microbial Ecology Life Sciences, Environmental Sciences, Fresh Water Studies, Geochemistry, Hydrology, Sedimentology
Freshwater suspended particulate matter (SPM) plays an important role in many biogeochemical cycles and serves multiple ecosystem functions. Most SPM is present as complex floc-like aggregate structures composed of various minerals and organic matter from the molecular to the organism level. Flocs provide habitat for microbes and feed for larger organisms. They constitute microbial bioreactors, [...]
Early evolution of the Adelaide Superbasin
Published: 2022-02-16
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy, Tectonics and Structure
Continental rifts have a significant role in supercontinent breakup, and the development of sedimentary basins. The Australian Adelaide Superbasin is one of the largest and best-preserved rift systems that initiated during the breakup of Rodinia, yet substantial challenges still hinder our understanding of its early evolution and place within the Rodinian supercontinent. In the past decade, our [...]
PyMelt: An extensible Python engine for mantle melting calculations
Published: 2022-02-13
Subjects: Earth Sciences, Geochemistry, Geology, Geophysics and Seismology, Volcanology
Modelling the melting of Earth’s mantle is crucial for understanding the distribution of volcanic activity on Earth and for testing models of mantle convection and mantle lithological heterogeneity. PyMelt is a new open-source Python library for calculating the melting behaviour of multi-lithology mantle and can be used to predict a number of geophysical and petrological observations, including [...]
Macrostratigraphy of the Ediacaran System in North America
Published: 2022-02-11
Subjects: Earth Sciences, Geochemistry, Geology, Paleontology, Sedimentology, Stratigraphy, Tectonics and Structure
Ediacaran sediments record the termination of Cryogenian ‘Snowball Earth’ glaciations, preserve the first occurrences of macroscopic metazoans, and contain one of the largest known negative δ13C excursions (the Shuram-Wonoka). The rock record for the transition between the Proterozoic and Phanerozoic in North America is also physically distinct, with much of the continent characterized by a wide [...]