Preprints
Filtering by Subject: Geochemistry
Oxidized Mantle Sources of HIMU and EM-type Ocean Island Basalts
Published: 2021-08-31
Subjects: Earth Sciences, Geochemistry, Geology
Oxygen fugacity (fO2) is a fundamental variable in igneous petrology with utility as a potential tracer of recycled surficial materials in the sources of mantle-derived lavas. It has been postulated that ocean island basalts (OIB) have elevated fO2 relative to mid-ocean ridge basalts (MORB) owing to more oxidized source regions. To clarify this issue, trace-element systematics of olivine grains [...]
Safety and Belonging in the Field: A Checklist for Educators
Published: 2021-08-19
Subjects: Atmospheric Sciences, Biogeochemistry, Climate, Cosmochemistry, Earth Sciences, Education, Environmental Education, Environmental Health and Protection, Environmental Indicators and Impact Assessment, Environmental Monitoring, Environmental Sciences, Environmental Studies, Fresh Water Studies, Geochemistry, Geographic Information Sciences, Geography, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Higher Education, Human Geography, Hydrology, Life Sciences, Meteorology, Mineral Physics, Natural Resource Economics, Natural Resources and Conservation, Natural Resources Management and Policy, Nature and Society Relations, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Oil, Gas, and Energy, Other Earth Sciences, Other Environmental Sciences, Other Geography, Other Oceanography and Atmospheric Sciences and Meteorology, Other Planetary Sciences, Outdoor Education, Paleobiology, Paleontology, Physical and Environmental Geography, Physical Sciences and Mathematics, Planetary Biogeochemistry, Planetary Geochemistry, Planetary Geology, Planetary Geomorphology, Planetary Geophysics and Seismology, Planetary Glaciology, Planetary Hydrology, Planetary Mineral Physics, Planetary Sciences, Planetary Sedimentology, Remote Sensing, Sedimentology, Social and Behavioral Sciences, Soil Science, Spatial Science, Speleology, Stratigraphy, Sustainability, Tectonics and Structure, Volcanology, Water Resource Management
Ensuring taught fieldwork is a positive, generative, collective, and valuable experience for all participants requires considerations beyond course content. To guarantee safety and belonging, participants’ identities (backgrounds and protected characteristics) must be considered as a part of fieldwork planning and implementation. Furthermore, getting fieldwork right is an important step in [...]
Dissolution precipitation creep as a process for the strain localisation in mafic rocks
Published: 2021-08-17
Subjects: Earth Sciences, Geochemistry, Tectonics and Structure
Unaltered mafic rocks consist of mechanically strong minerals (e.g. pyroxene, plagioclase and garnet) that can be deformed by crystal plastic mechanisms only at high temperatures (>800°C). Yet, many mafic rocks do show extensive deformation by non-brittle mechanisms when they have been subjected to lower temperature conditions. In such cases, the deformation typically is assisted by mineral [...]
A strontium isoscape of Italy for provenance studies
Published: 2021-08-06
Subjects: Geochemistry
We present a novel database of environmental and geological 87Sr/86Sr values (n = 1920) from Italy, using literature data and newly analysed samples, for provenance purposes. We collected both bioavailable and non-bioavailable (i.e. rocks and bulk soils) data to attain a broader view of the Sr isotope variability of the Italian peninsula. These data were used to build isotope variability maps, [...]
Impact of Zn Substitution on Fe(II)-induced Ferrihydrite Transformation Pathways
Published: 2021-07-29
Subjects: Geochemistry
Iron oxide minerals are ubiquitous in soils, sediments, and aquatic systems and influence the fate and availability of trace metals. Ferrihydrite is a common iron oxide of nanoparticulate size and poor crystallinity, serving as a thermodynamically unstable precursor to more crystalline phases. While aging induces such phase transformations, these are accelerated by the presence of dissolved [...]
Strengths and limitations of in situ U-Pb titanite petrochronology in polymetamorphic rocks: An example from western Maine, USA.
Published: 2021-07-29
Subjects: Earth Sciences, Geochemistry, Geology, Other Earth Sciences, Physical Sciences and Mathematics, Tectonics and Structure
Titanite is a potentially powerful U-Pb petrochronometer that may record metamorphism, metasomatism, and deformation. Titanite may also incorporate significant inherited Pb, the correction for which may introduce inaccuracies and result in geologically ambiguous U-Pb dates. Here we present laser ablation inductively coupled mass spectrometry (LA-ICP-MS)-derived titanite U-Pb dates and trace [...]
Kyanite petrogenesis in migmatites: Resolving melting and metamorphic signatures
Published: 2021-07-26
Subjects: Earth Sciences, Geochemistry, Geology
Aluminosilicates (kyanite, sillimanite and andalusite) are useful pressure-temperature (P-T) indicators that can form in a range of rock types through different mineral reactions, including those that involve partial melting. Their involvement in melting reactions means that the presence of aluminosilicates in migmatite mineral assemblages can help to (broadly) constrain the P-T conditions of [...]
Creating a Diamond Open Access community journal for Seismology and Earthquake Science
Published: 2021-07-22
Subjects: Earth Sciences, Geochemistry, Geology, Geophysics and Seismology, Tectonics and Structure
On 24 November 2020, the Springer Nature publishing group announced the introduction of Open Access (OA) articles in Nature and its sibling journals. The corresponding OA publication fee (charged directly to the authors) was set to €9,500/$11,390/£8,290, an amount that may be well out of reach for many researchers. This is especially a problem for researchers in developing countries, early-career [...]
Created by the Monte Peron rock avalanche: Lago di Vedana (Dolomites, Italy) and its sediment record of landscape evolution after a mass wasting event
Published: 2021-07-09
Subjects: Earth Sciences, Geochemistry, Geology, Geomorphology
The timing of the Monte Peron Landslide is revised to 2890 cal. BP based on a radiocarbon-dated sediment stratigraphy of Lago di Vedana. This age fosters the importance of hydroclimatic triggers in the light of accelerating global warming with a predicted increase of precipitation enhancing the regional predisposition to large landslides. Moreover, a layer enriched in allochthonous organic and [...]
Carbonate polymorphism controlled by microbial iron redox dynamics at a natural CO2 leakage site (Crystal Geyser, Utah)
Published: 2021-07-07
Subjects: Geochemistry, Geology, Sedimentology
Crystal Geyser (Utah, USA) is a CO2-rich low-temperature geyser that is studied as a natural analog for CO2 leakage from carbon capture and storage (CCS) sites. In order to better constrain the biogeochemical processes influencing CaCO3 precipitation at geological CO2 escape sites, we characterized fast-forming iron-rich calcium carbonate pisoids and travertines precipitating from the fluids [...]
Cosmogenic 3He in terrestrial rocks: a review
Published: 2021-07-05
Subjects: Earth Sciences, Geochemistry, Geology, Geomorphology, Glaciology, Other Earth Sciences
This review article summarizes the state of the art of cosmogenic 3He (3Hec), with a focus on the most efficient methods and strategies for measuring this cosmogenic noble gas in the terrestrial minerals. Our ability to accurately and precisely measure cosmogenic 3He in minerals is mainly constrained by the level of the non-cosmogenic 3He background (i.e., magmatic, radiogenic, nucleogenic, and [...]
Machine learning thermobarometry and chemometry using amphibole and clinopyroxene: a window into the roots of an arc volcano (Mount Liamuiga, Saint Kitts)
Published: 2021-07-04
Subjects: Earth Sciences, Geochemistry, Mineral Physics, Stratigraphy, Volcanology
The physical and chemical properties of magma govern the eruptive style and behaviour of volcanoes. Many of these parameters are linked to the storage pressure and temperature of the erupted magma, and melt chemistry. However, reliable single-phase thermobarometers and chemometers which can recover this information, particularly using amphibole chemistry, remain elusive. We present a suite of [...]
Late Quaternary climatic histories from the Hermes Cave, Corinth Rift, Greece
Published: 2021-06-25
Subjects: Earth Sciences, Geochemistry, Geomorphology, Sedimentology, Speleology
The Greek peninsula is located at the crossroads of several major atmospheric circulation patterns and is consequently characterized by high variability in climatic conditions, making it an important location to examine past climate variability. Over the last decades, the focus of many studies in the region has been to unravel Holocene paleoclimatic oscillations and their impact on the [...]
Environmental variability at the margin of the South American Monsoon System recorded by a high-resolution sediment record from Lagoa Dourada (South Brazil)
Published: 2021-06-25
Subjects: Earth Sciences, Geochemistry, Geomorphology, Sedimentology
High-resolution geochemical and sedimentological data have been obtained for a lacustrine sediment record from Lagoa Dourada (South Brazil). Four distinctly different depositional processes were determined: (1) Suspension fallout of fine-grained minerogenic particles transferred via fluvial activity dominates the Early Holocene and relates to open grassland in the catchment area; (2) Activation [...]
Bayesian population correlation: A probabilistic approach to inferring and comparing population distributions for detrital zircon ages
Published: 2021-06-18
Subjects: Geochemistry, Probability, Statistical Methodology, Tectonics and Structure
Populations of detrital zircons are shaped by geologic factors such as sediment transport, erosion mechanisms, and the zircon fertility of source areas. Zircon U-Pb age datasets are influenced both by these geologic factors and by the statistical effects of sampling. Such statistical effects introduce significant uncertainty into the inference of parent population age distributions from detrital [...]