Preprints
Filtering by Subject: Geochemistry
Lithologic Controls on Silicate Weathering Regimes of Temperate Planets
Published: 2021-03-12
Subjects: Astrophysics and Astronomy, Earth Sciences, Geochemistry, Planetary Geochemistry, Planetary Sciences
Weathering of silicate rocks at a planetary surface can draw down CO2 from the atmosphere for eventual burial and long-term storage in the planetary interior. This process is thought to provide essential negative feedback to the carbonate-silicate cycle (carbon cycle) to maintain clement climates on Earth and potentially similar temperate exoplanets. We implement thermodynamics to determine [...]
The Ca and Mg isotope record of the Cryogenian Trezona carbon isotope excursion
Published: 2021-03-11
Subjects: Earth Sciences, Geochemistry, Geology, Sedimentology, Stratigraphy
The Trezona carbon isotope excursion is recorded on five different continents in platform carbonates deposited prior to the end-Cryogenian Marinoan glaciation (>635 Ma) and represents a change in carbon isotope values of 16-18 per mill. Based on the spatial and temporal reproducibility, the excursion previously has been interpreted as tracking the carbon isotopic composition of dissolved [...]
Crisis at the Salton Sea: The Vital Role of Science
Published: 2021-03-03
Subjects: Atmospheric Sciences, Biogeochemistry, Chemistry, Climate, Earth Sciences, Environmental Chemistry, Environmental Public Health, Environmental Sciences, Environmental Studies, Geochemistry, Geology, Geomorphology, Hydrology, Medicine and Health Sciences, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics, Public Health, Social and Behavioral Sciences
The Salton Sea—a hypersaline, terminal lake in southern California—is in crisis. A combination of mismanagement and competition among federal, state and local agencies has hindered efforts to address declining lake levels and unstable water chemistry. This delay has heightened the public health threat to regional communities as retreating shorelines expose dry lakebed— a source of potentially [...]
Evidence for crustal removal, tectonic erosion and flare-ups from the Japanese evolving forearc sediment provenance
Published: 2021-02-24
Subjects: Earth Sciences, Geochemistry, Geology, Tectonics and Structure
Forearc basins preserve the geologic record relating strictly to arc magmatism. The provenance of forearc sediment can be used to differentiate periods of crustal growth, accretion, and destruction, enhanced magmatism, advancing and retreating subduction slabs, delamination, etc. All these tectonic events systems predict differing degrees of sedimentary reworking of the older forearc units. [...]
Insights into the nature of plume-ridge interaction and outflux of H2O from the Galápagos Spreading Centre
Published: 2021-02-18
Subjects: Earth Sciences, Geochemistry, Other Earth Sciences, Physical Sciences and Mathematics, Volcanology
The flow of high-temperature and compositionally-enriched material between mantle plumes and nearby spreading centres influences up to 30% of the global mid-ocean ridge system and represents a significant, but currently unconstrained, flux of volatiles out of the mantle. Here we present new analyses of H2O, F, Cl and S in basaltic glass chips from an archetypal region of plume-ridge interaction, [...]
234U/230Th coral growth dating yields reliable ages in restricted basins despite anomalous δ234Ui values
Published: 2021-02-10
Subjects: Geochemistry, Geology, Tectonics and Structure
Late Quaternary coral growth ages from uplifted coastal regions, such as marine terraces and associated palaeoshorelines, are an essential tool used to derive tectonic and fault controlled uplift and deformation rates, and thus contribute to seismic hazard analysis and constrain past global sea levels. Fossil coral growth ages are assessed for reliability based upon whether the δ234Ui (or [...]
Classification, segmentation and correlation of zoned minerals
Published: 2021-02-01
Subjects: Earth Sciences, Environmental Sciences, Geochemistry, Geology, Numerical Analysis and Scientific Computing, Statistics and Probability, Volcanology
Minerals exhibit zoning patterns that can be related to changes in the environment in which they grew. Using statistical methods that have been designed to segment optical images, we have developed a procedure to segment zonation within minerals and correlate these zones between multiple crystals using elemental maps. This allows us to quantify the complexity and variability of chemical zoning [...]
Ordination analysis in sedimentology, geochemistry and paleoenvironment - background, current trends and recommendations
Published: 2021-02-01
Subjects: Biogeochemistry, Earth Sciences, Environmental Indicators and Impact Assessment, Environmental Monitoring, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Multivariate Analysis, Oil, Gas, and Energy, Other Earth Sciences, Paleobiology, Paleontology, Sedimentology
Ordination is the name given to a group of methods used to analyze multiple variables without preceding hypotheses. Over the last few decades the use of these methods in Earth science in general, and notably in analyses of sedimentary sources, has dramatically increased. However, with limited resources oriented towards Earth scientists on the topic, the application of ordination analysis is at [...]
Quantitative chemical mapping of plagioclase as a tool for the interpretation of volcanic stratigraphy: an example from Saint Kitts, Lesser Antilles
Published: 2021-02-01
Subjects: Earth Sciences, Geochemistry, Geology, Stratigraphy, Volcanology
Establishing a quantitative link between magmatic processes occurring at depth and volcanic eruption dynamics is essential to forecast the future behaviour of volcanoes, and to correctly interpret monitoring signals at active centres. Chemical zoning in minerals, which captures successive events or states within a magmatic system, can be exploited for such a purpose. However, to develop a [...]
Observational estimates of dynamic topography through space and time
Published: 2021-01-24
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Paleobiology, Physical Sciences and Mathematics, Sedimentology, Stratigraphy, Tectonics and Structure, Volcanology
Earth's mantle undergoes convection on million-year timescales as heat is transferred from depth to the surface. Whilst this flow has long been linked to the large-scale horizontal forces that drive plate tectonics and supercontinent cycles, geologists are increasingly recognising the signature of convection through transient vertical motions in the rock record, known as "dynamic topography". A [...]
Evidence confirms an anthropic origin of Amazonian Dark Earths
Published: 2021-01-22
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geomorphology, Physical Sciences and Mathematics, Soil Science
First described over 120 years ago in Brazil, Amazonian Dark Earths (ADEs) are expanses of dark soil that are exceptionally fertile and contain large quantities of archaeological artefacts. The elevated fertility of the dark and often deep A horizon of ADEs is widely regarded as an outcome of pre-Columbian human influence. Controversially, in their recent paper Silva et al.2argue that the higher [...]
Integrated magnetotelluric and petrological analysis of felsic magma reservoirs: Insights from Ethiopian rift volcanoes
Published: 2021-01-16
Subjects: Earth Sciences, Geochemistry, Geophysics and Seismology, Volcanology
Geophysical and petrological probes are key to understanding the structure and the thermochemical state of active magmatic systems. Recent advances in laboratory analyses, field investigations and numerical methods have allowed increasingly complex data-constraint models with new insights into magma plumbing systems and melt evolution. However, there is still a need for methods to quantitatively [...]
Mixing between chemically variable primitive basalts creates and modifies crystal cargoes
Published: 2021-01-13
Subjects: Geochemistry
Basaltic crystal cargoes often preserve records of mantle-derived chemical variability that have been erased from their carrier liquids by magma mixing. However, the consequences of mixing between similarly primitive but otherwise chemically variable magmas remain poorly understood despite ubiquitous evidence of chemical variability in primary melt compositions and mixing-induced disequilibrium [...]
Differences in carbon isotope discrimination between angiosperm and gymnosperm woody plants, and their geological significance
Published: 2020-12-13
Subjects: Biogeochemistry, Climate, Geochemistry, Oceanography and Atmospheric Sciences and Meteorology, Paleobiology
For most of the Phanerozoic Eon, Earth’s woody vegetation has been dominated by C3 plants – predominantly gymnosperms - with angiosperms only emerging as the dominant plant group as CO2 declined during the Cenozoic (66 Ma onward). At present, differences in carbon isotope discrimination (Δ13C) between angiosperm and gymnosperm plants are relatively small (2–3 ‰), but an increasing body of [...]
VESIcal Part I: An open-source thermodynamic model engine for mixed volatile (H2O-CO2) solubility in silicate melts
Published: 2020-12-08
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Planetary Geochemistry, Planetary Geology, Planetary Sciences, Volcanology
Thermodynamics has been fundamental to the interpretation of geologic data and modeling of geologic systems for decades. However, more recent advancements in computational capabilities and a marked increase in researchers’ accessibility to computing tools has outpaced the functionality and extensibility of currently available modeling tools. Here we present VESIcal (Volatile Equilibria and [...]