Preprints
Filtering by Subject: Geochemistry
Stalagmite carbon isotopes suggest deglacial increase in soil respiration in Western Europe driven by temperature change
Published: 2020-12-03
Subjects: Biogeochemistry, Climate, Earth Sciences, Geochemistry, Physical Sciences and Mathematics, Speleology
The temperate region of Western Europe underwent dramatic climatic and environmental change during the last deglaciation. Much of what is known about the terrestrial ecosystem response to deglacial warming stems from pollen preserved in sediment sequences, providing information on vegetation composition. Other ecosystem processes, such as soil respiration, remain poorly constrained over past [...]
Chemistry speedup in reactive transport simulations: purely data-driven and physics-based surrogates
Published: 2020-11-30
Subjects: Earth Sciences, Geochemistry
The computational costs associated with coupled reactive transport simulations are mostly due to the chemical subsystem: replacing it with a pre-trained statistical surrogate is a promising strategy to achieve decisive speedups at price of small accuracy losses and thus to extend the scale of problems which can be handled. We introduce a hierarchical coupling scheme in which ``full [...]
A Vision for the Future Low-Temperature Geochemical Data-scape
Published: 2020-11-21
Subjects: Biogeochemistry, Computer Sciences, Databases and Information Systems, Earth Sciences, Environmental Sciences, Geochemistry, Geology, Geomorphology, Hydrology, Other Computer Sciences, Other Earth Sciences, Soil Science
Data sharing benefits the researcher, the scientific community, and most importantly, the public by enabling more impactful analysis of data and greater transparency in scientific research. However, like many other scientists, the low-temperature geochemistry (LTG) community has generally not developed protocols and standards for publishing, citing, and versioning datasets. This paper is the [...]
Boron isotopic signatures of melt inclusions from North Iceland reveal recycled material in the Icelandic mantle source
Published: 2020-11-13
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Volcanology
Trace element and volatile heterogeneity in the Earth's mantle is in uenced by the recycling of oceanic lithosphere through subduction. Oceanic island basalts commonly have high concentrations of volatiles compared to mid-ocean ridge basalts, but the extent to which this enrichment is linked to recycled mantle domains remains unclear. Boron is an ideal tracer of recycled subducted material, [...]
1600 year-long sedimentary record of tsunamis and hurricanes in the Lesser Antilles (Scrub Island, Anguilla)
Published: 2020-10-22
Subjects: Geochemistry, Oceanography, Sedimentology
The Lesser Antilles are a densely populated and a very touristic region exposed to many short-term hazards such as hurricanes and tsunamis. However, the historical catalog of these events is too short to allow risk assessment and return period estimations, and it needs to be completed with long-term geological records. Two sediment cores were sampled in March 2018 in a small coastal lagoon on [...]
Modulation of riverine concentration-discharge relationships by changes in the shape of the water transit time distribution
Published: 2020-10-21
Subjects: Geochemistry, Hydrology
The concentrations of weathering-derived solutes in rivers and their co-variance with discharge are thought to reflect reactive-transport processes in hillslopes and to reveal the sensitivity of solute fluxes to climatic change. It is expected that discharge-driven changes in water transit times play some role in setting concentration-discharge (C-Q) relationships, but knowledge gaps remain. To [...]
The global melt inclusion C/Ba array: mantle variability, melting process, or degassing?
Published: 2020-10-21
Subjects: Earth Sciences, Geochemistry
The Earth’s mantle holds more carbon than its oceans, atmosphere and continents combined, yet the distribution of carbon within the mantle remains uncertain. Our best constraints on the distribution of carbon within the upper mantle are derived from the carbon-trace element systematics of ultra-depleted glasses and melt inclusions from mid-ocean ridge basalts. However, carbon-trace element [...]
Dynamics of core-mantle separation: influence of viscosity contrast and metal/silicate partition coefficients on the chemical equilibrium
Published: 2020-10-21
Subjects: Earth Sciences, Geochemistry, Geophysics and Seismology, Physical Sciences and Mathematics
The composition of the Earth's core and mantle is set by the chemical equilibrium between metals and silicates during core/mantle segregation. The metallic core separated from the mantle by gravitational descent in the form of diapirs in a magma ocean, and therefore the dynamics of the diapir's downward movement has an influence on the chemical equilibrium. In this study, we characterize the [...]
Amphibole Control on Copper Systematics in Arcs: Insights from the Analysis of Global Datasets
Published: 2020-10-21
Subjects: Earth Sciences, Geochemistry, Geology, Volcanology
Copper, sourced from porphyry deposits formed in arc settings, is a critical resource, and is primarily sourced from magmas. However, the processes that shape the copper contents of arc magmas are up for debate. Existing models place emphasis on different petrological agents that explain large-scale trends in copper systematics. Previous studies have noted the 'Cu paradox,' where the magmas with [...]
A machine learning approach for prioritizing groundwater testing for per-and polyfluoroalkyl substances (PFAS)
Published: 2020-10-19
Subjects: Environmental Engineering, Environmental Health and Protection, Environmental Monitoring, Geochemistry, Hydrology, Risk Analysis, Water Resource Management
Regulatory agencies are beginning to recognize and regulate per-and polyfluoroalkyl substances (PFAS) as concerning environmental contaminants. In groundwater management, testing and mitigation strategies are desirable, but can be time and cost-intensive processes. As a result, only a fraction of all groundwater wells has been tested for PFAS levels, resulting in potentially extended drinking [...]
The composition and weathering of the continents over geologic time
Published: 2020-08-21
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The composition of continental crust records a history of construction by tectonics and destruction by physical and chemical erosion. Quantitative constraints on how both igneous addition and chemical weathering have modified the continents bulk composition are essential for understanding the evolution of geodynamics and climate. We have extracted temporal trends in sediments protolith [...]
Apatite fission-track dating by LA-Q-ICP-MS mapping
Published: 2020-08-17
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics
Obtaining accurate and precise apatite fission-track (AFT) ages is dependent on producing plentiful high-quality apatite grains from a sample, ideally with high spontaneous fission-track densities (c. >105 tracks.cm-2). Many natural samples, such as bedrock samples from young orogenic belts or low-grade metamorphic samples with low U contents yield low spontaneous fission-track densities. Such [...]
Marine mineral-catalyzed NO and N2O formation on the anoxic early Earth
Published: 2020-08-17
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Microbial metabolisms were limited by available terminal electron acceptors in the anoxic environment of the early Archean. However, iron mineral phases in Fe2+-rich (ferruginous) oceans could have catalyzed reactions with abiotically fixed nitrogen leading to the formation of nitrous oxide (N2O), a potentially favorable terminal electron acceptor. We experimentally simulated anoxic [...]
Hydrogeologic and Geochemical Distinctions in Salar Freshwater Brine Systems
Published: 2020-08-05
Subjects: Earth Sciences, Geochemistry, Hydrology, Physical Sciences and Mathematics
The Salar de Atacama contains one of the world’s most important lithium resources and hosts unique and fragile desert ecosystems. Water use issues of the hyper-arid region have placed it at the center of global attention. This investigation is the first robust assessment of a salar system to incorporate geology, hydrogeology, and geochemistry of the aquifer system in the inflow, transition zone [...]
Whats down there? The structures, materials and environment of deep-seated tremor and slip
Published: 2020-07-16
Subjects: Earth Sciences, Geochemistry, Geology, Geophysics and Seismology, Physical Sciences and Mathematics, Tectonics and Structure
Episodic tremor and slow slip (ETS) events occur downdip of the seismogenic zone of numerous subduction megathrusts and plate boundary strike-slip faults. These events represent a fascinating and perplexing mode of fault failure that has greatly broadened our view of earthquake dynamics. In this contribution, we review constraints on the ETS deformation process from both geophysical observations [...]