Preprints
Filtering by Subject: Geochemistry
Preservation of Organic Carbon in Dolomitized Cambrian Stromatolites and Implications for Microbial Biosignatures in Diagenetically Replaced Carbonate Rock
Published: 2020-05-26
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Planetary Geology, Planetary Sciences
Stromatolites have been a major focus in the search for ancient microbial life, however, the organic carbon biosignatures of dolomitized stromatolites have not yet been fully characterized or correlated with their dolomitizing conditions. Although dolomitization rarely preserves microbial morphology, the presence of organic carbon can provide valuable information for characterization of fossils’ [...]
River sediment geochemistry as a conservative mixture of source regions: Observations and predictions from the Cairngorms, UK
Published: 2020-05-25
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The elemental composition of sediments in rivers is the product of physical and chemical erosion of rocks, which is then transported across drainage networks. A corollary is that fluvial sedimentary geochemistry can be used to understand geologic, climatic and geomorphic processes. We develop a simple methodology to predict elemental compositions of river sediments from digital elevation data and [...]
Cave airflow patterns control calcite dissolution rates within a cave stream: Blowing Springs Cave, Arkansas, USA
Published: 2020-05-25
Subjects: Earth Sciences, Environmental Sciences, Geochemistry, Geomorphology, Hydrology, Physical Sciences and Mathematics
Erosion rates within streams vary dramatically over time, as differences in discharge and sediment load enhance or inhibit erosion processes. Within cave streams, and other bedrock channels incising soluble rocks, changes in water chemistry are an important factor in determining how erosion rates will vary in both time and space. Prior studies within surface streams, springs, and caves suggest [...]
Upper mantle mush zones beneath low melt flux ocean island volcanoes: insights from Isla Floreana, Galápagos
Published: 2020-05-25
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics, Volcanology
The physicochemical characteristics of sub-volcanic magma storage regions have important implications for magma system dynamics and pre-eruptive behaviour. The architecture of magma storage regions located directly above high buoyancy flux mantle plumes (such as Kīlauea, Hawai’i and Fernandina, Galápagos) are relatively well understood. However, far fewer constraints exist on the nature of magma [...]
Holocene tephrochronology of Kerguelen Archipelago, Subantarctic Indian Ocean
Published: 2020-05-20
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics, Sedimentology, Stratigraphy, Volcanology
Up to now, no geochemical or geochronological data has been published about Holocene volcanic activity on the Kerguelen Archipelago. Here we present the first continuous Holocene chronology of volcanic eruptions on the archipelago. We compared sedimentological, geochronological and geochemical data from two lake sediment cores taken in two different depocenters of Lake Armor, located ca. 70 km [...]
Jarosite formation in deep Antarctic ice provides a window into acidic, water-limited weathering on Mars
Published: 2020-05-20
Subjects: Cosmochemistry, Earth Sciences, Geochemistry, Physical Sciences and Mathematics, Planetary Geochemistry, Planetary Glaciology, Planetary Sciences
Many interpretations have been proposed to explain the presence of jarosite within Martian surficial sediments, including the possibility that it precipitated within paleo-ice deposits owing to englacial weathering of dust. But until now a similar mechanism was not observed on Earth nor in other planetary settings. We report the first multi-analytical indication of jarosite formation within deep [...]
Constraining crustal silica on ancient Earth
Published: 2020-05-07
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics
Accurately quantifying the composition of continental crust on Hadean and Archean Earth is critical to our understanding of the physiography, tectonics, and climate of our planet at the dawn of life. One longstanding paradigm involves the growth of a relatively mafic planetary crust over the first 1-2 billion years of Earth history, implying a lack of modern plate tectonics, a paucity of [...]
Do olivine crystallization temperatures faithfully record mantle temperature variability?
Published: 2020-05-07
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Crystallization temperatures of primitive olivine crystals have been widely used as both a proxy for, or an intermediate step in calculating, mantle temperatures. The olivine-spinel aluminum-exchange thermometer has been applied to samples from mid-ocean ridges and large igneous provinces, yielding considerable variability in olivine crystallization temperatures. We supplement the existing data [...]
Lateral variations in lower crustal strength control the temporal evolution of mountain ranges: examples from south-east Tibet
Published: 2020-04-17
Subjects: Earth Sciences, Geochemistry, Geomorphology, Geophysics and Seismology, Physical Sciences and Mathematics, Tectonics and Structure
Controversy surrounds the rheology of the continental lithosphere, and how it controls the evolution and behaviour of mountain ranges. In this study, we investigate the effect of lateral contrasts in the strength of the lower crust, such as those between cratonic continental interiors and weaker rocks in the adjacent deforming regions, on the evolution of topography. We combine numerical [...]
Rethinking Groundwater Age
Published: 2020-04-03
Subjects: Earth Sciences, Geochemistry, Hydrology, Physical Sciences and Mathematics
The ideas that old or “fossil” groundwater cannot be pumped sustainably, or that recently recharged groundwater is inherently sustainable are both mistaken. Both old and young groundwaters can be used in physically sustainable or unsustainable ways.
International disparities in open access practices of the Earth Sciences community
Published: 2020-03-31
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Hydrology, Library and Information Science, Mineral Physics, Other Earth Sciences, Paleobiology, Paleontology, Physical Sciences and Mathematics, Sedimentology, Social and Behavioral Sciences, Soil Science, Speleology, Stratigraphy, Tectonics and Structure, Volcanology
Short communication on international disparities in open access practices of the Earth Sciences community
On the potential of preprints in geochemistry: the good, the bad and the ugly
Published: 2020-03-21
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Library and Information Science, Physical Sciences and Mathematics, Social and Behavioral Sciences
Short communication on the use of preprint in geochemistry
Mechanistic insights into sulfur rich oil formation, relevant to geological carbon storage routes. A study using (+) APPI FTICR-MS analysis
Published: 2020-03-03
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Sulfur incorporation into sedimentary organic matter has a key role in carbon preservation in the geosphere. Such processes can inform strategies for human timescale carbon storage to mitigate climate change impacts and thus more detailed knowledge of sulfur incorporation into biomass species is needed. Until recently, detailed chemical characterization of sulfurized organic matter was only [...]
Magma diversity reflects recharge regime and thermal structure of the crust
Published: 2020-03-03
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Volcanology
The chemistry of magmas erupted by volcanoes is a message from deep within the Earth’s crust, which if decrypted, can provide essential information on magmatic processes occurring at inaccessible depths. While some volcanoes are prone to erupt magmas of a wide compositional variety, others sample rather monotonous chemistries through time. Whether such differences are a consequence of physical [...]
Constraining mechanisms of quartz precipitation during silicification and chemical sedimentation in the in the ~2.7 Ga Abitibi Greenstone Belt, Canada
Published: 2020-03-03
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Silica-rich Precambrian rocks often preserve geochemical information and microfossil remnants from the early biosphere. Because these rocks are such critical geochemical and paleontological archives, we need robust tools to identify the chemical and physical conditions under which siliceous Precambrian rocks form, and determine how such information links to the specific depositional environment. [...]