Preprints
Filtering by Subject: Geochemistry
Effects of aseismic ridge subduction on geochemistry of frontal arc magmas
Published: 2019-12-13
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Aseismic ridge subduction is considered to exert major controls on volcanic activity, formation of porphyry Cu-Au deposits and the generation of juvenile Earth’s crust. Yet, there are almost no studies that have addressed in a systematic way the effects of this process on the geochemistry of arc magmas. Here we explore the role of the subducted aseismic Carnegie ridge on modulating frontal arc [...]
Open Access publishing practice in Geochemistry: current state and look to the future
Published: 2019-12-08
Subjects: Biogeochemistry, Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Open Access (OA) describes the free, unrestricted access to and re-use of research articles. Recently, a new wave of interest, debate, and practice surrounding OA publishing has emerged. In this paper, we provide a simple overview of the trends in OA practice in the broad field of geochemistry. Characteristics of the approach such as whether or not an article processing charge (APC) exists, what [...]
U-Th dating of lake sediments: Lessons from the 700 kyr sediment record of Lake Junín, Peru
Published: 2019-12-08
Subjects: Earth Sciences, Geochemistry, Geology, Other Earth Sciences, Physical Sciences and Mathematics, Sedimentology
*----- NOTE: This is a peer reviewed preprint of a paper accepted in Quaternary Science Reviews as of June 8, 2020 -----* Deep sediment cores from long-lived lake basins are fundamental records of paleoenvironmental history, but the power of these reconstructions has often been limited by poor age control. Uranium-thorium (U-Th) dating has the potential to fill a gap in current geochronological [...]
Ferruginous oceans during OAE1a and collapse of the marine sulfate pool
Published: 2019-12-05
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
Seawater sulfate is one of the largest oxidant pools at Earth’s surface today and its concentration in the oceans is generally assumed to have varied between 5 and 28 mM since the early Phanerozoic Eon. Intermittent and potentially global Oceanic Anoxic Events (OAEs) are accompanied by changes in seawater sulfate concentrations and signal perturbations in the Earth system associated with major [...]
Abrupt Arctic Warming Repeatedly Led to Prolonged Drought and Glacial Retreat in the Tropical Andes During the Last Glacial Cycle
Published: 2019-12-03
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Sedimentology
A sediment core spanning the last ~50 ka from Lake Junín (Peru) in the tropical Andes reveals abrupt climatic events on a centennial-millennial time scale. These events, which involved the near-complete disappearance of glaciers below 4700 masl in the eastern Andean cordillera and major reductions in the level of Peru’s second largest lake, occurred during the abrupt warmings recorded in [...]
Revised timing of Cenozoic Atlantic incursions and changing hinterland sediment sources during southern Patagonian orogenesis
Published: 2019-11-21
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Stratigraphy
New detrital zircon U-Pb geochronology data from the Cenozoic Magallanes-Austral Basin in Argentina and Chile ~51°S establish a revised chronostratigraphy of Paleocene – Miocene foreland synorogenic strata and document the rise and subsequent isolation of hinterland sources in the Patagonian Andes from the continental margin. The upsection loss of zircons derived from the hinterland Paleozoic and [...]
Ultramafic rock carbonation: Constraints from listvenite core BT1B, Oman Drilling Project
Published: 2019-11-14
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics, Other Earth Sciences, Physical Sciences and Mathematics
The occurrence of the quartz–carbonate alteration assemblage (listvenite) in ophiolites indicates that ultramafic rock represents an effective sink for dissolved CO2. However, the majority of earlier studies of ultramafic rock carbonation had to rely on the surface exposure of reaction textures and field relationships. Here we present the first observations on ultramafic rock alteration obtained [...]
The Fate of Carbon during Earth’s Core–Mantle Differentiation
Published: 2019-11-14
Subjects: Earth Sciences, Geochemistry, Mineral Physics, Physical Sciences and Mathematics
Carbon is an essential element for the existence and evolution of life on Earth, constitutes up to 50% of dry biomass, and is likely a requirement for all life in the universe. Its high abundance in Earth’s crust and mantle (the Bulk Silicate Earth, BSE) is surprising because carbon is strongly siderophile (metal-loving) and should have segregated almost completely into Earth’s core during [...]
Ancient subducted oceans controlling the positioning of deep mantle plumes
Published: 2019-11-08
Subjects: Earth Sciences, Geochemistry, Geophysics and Seismology, Physical Sciences and Mathematics, Tectonics and Structure
Seismic imaging of the Earths interior reveals plumes originating from relatively hot regions of the lower mantle, surrounded by cooler material thought to be remnants of ancient subducted oceans. Based largely on geophysical data, two opposing hypotheses dominate the discussion on dynamics at the base of mantle: the large hot anomalies are thermo-chemical in nature; or, alternatively, they are [...]
Growth, overprinting, and stabilization of Proterozoic Provinces in the southern Lake Superior region
Published: 2019-11-07
Subjects: Earth Sciences, Geochemistry, Geology, Physical Sciences and Mathematics, Tectonics and Structure
New geochronologic data in the southern Lake Superior region provide key information on the timing and nature of tectonic activity that pre-and post-date initial Paleoproterozoic growth of Laurentia during the geon 18 Penokean orogeny. The obducted Pembine ophiolite formed along the edge of a Paleoproterozoic ocean basin at least 30 m.y. prior to Penokean island arc/microcontinent accretion [...]
The variation and visualisation of elastic anisotropy in rock-forming minerals
Published: 2019-10-31
Subjects: Earth Sciences, Geochemistry, Geology, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics, Tectonics and Structure
All minerals behave elastically, a rheological property that controls their ability to support stress, strain and pressure, the nature of acoustic wave propagation and influences subsequent plastic (i.e. permanent, non-reversible) deformation. All minerals are intrinsically anisotropic in their elastic properties – that is, they have directional variations that are related to the configuration [...]
On the difficulties of being rigorous in environmental geochemistry studies: some recommendations for designing an impactful paper
Published: 2019-10-25
Subjects: Biogeochemistry, Chemistry, Earth Sciences, Environmental Chemistry, Environmental Sciences, Geochemistry, Other Environmental Sciences, Physical Sciences and Mathematics
There have been numerous environmental geochemistry studies using chemical, geological, ecological and toxicological methods but each of these fields requires more subject specialist rigour than has generally been applied so far. Field-specific terminology has been misused and the resulting interpretations rendered inaccurate. In this paper, we propose a series of suggestions, based on our [...]
Major-element composition of sediments in terms of weathering and provenance: Implications for crustal recycling
Published: 2019-10-24
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The elemental composition of a sediment is set by the composition of its protolith and modified by weathering, sorting, and diagenesis. An important problem is deconvolving these contributions to a sediment’s composition to arrive at information about processes that operate on the Earth’s surface. We approach this problem by developing a predictive and invertible model of sedimentary [...]
River inflow dominates methane emissions in an Arctic coastal system
Published: 2019-10-13
Subjects: Biogeochemistry, Earth Sciences, Environmental Monitoring, Environmental Sciences, Fresh Water Studies, Geochemistry, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Physical Sciences and Mathematics
Measurements of greenhouse gases in Arctic waters are strongly biased toward low-ice summer conditions, with few observations during periods of seasonal ice retreat. We present a year-round time series of dissolved methane (CH4) and nitrous oxide (N2O), along with targeted observations during ice melt of CH4 and carbon dioxide (CO2) in a river and estuary adjacent to Cambridge Bay, Nunavut, [...]
Evolution of the melt source during protracted crustal anatexis; an example from the Bhutan Himalaya
Published: 2019-10-10
Subjects: Earth Sciences, Geochemistry, Physical Sciences and Mathematics
The chemical compositions of growth zones of magmatic zircon provide powerful insight into evolving magma compositions due to their ability to record both time and the local chemical environment. In situ U-Pb and Hf isotope analyses of zircon rims from Tertiary leucogranites of the Bhutan Himalaya reveal, for the first time, an evolution in melt composition between 32-12 Ma. The data indicate a [...]