Preprints
Filtering by Subject: Mineral Physics
Compressibility of ferropericlase at high-temperature: evidence for the iron spin crossover in seismic tomography
Published: 2023-04-06
Subjects: Earth Sciences, Geophysics and Seismology, Mineral Physics
The iron spin crossover in ferropericlase, the second most abundant mineral in Earth’s lower mantle, causes changes in a range of physical properties, including seismic wave velocities. Understanding the effect of temperature on the spin crossover is essential to detect its signature in seismic observations and constrain its occurrence in the mantle. Here, we report the first experimental results [...]
DiadFit: An Open-Source Python3 Tool for Peak fitting of Raman Data from silicate melts and CO2 fluids
Published: 2023-04-04
Subjects: Earth Sciences, Geology, Mineral Physics, Physical Sciences and Mathematics, Volcanology
We present DiadFit - an open-source Python3 tool for efficient processing of Raman spectroscopy data collected from fluidinclusions, melt inclusions and silicate melts. DiadFit is optimized to fit the characteristic peaks from CO2 fluids (Fermi diads,hot bands, 13C), gas species such as SO2, N2, solid precipitates (e.g., carbonates), and Ne emission lines with easily tweakablebackground positions [...]
Can homogeneous nucleation resolve the inner core nucleation paradox?
Published: 2023-03-24
Subjects: Condensed Matter Physics, Earth Sciences, Geophysics and Seismology, Mineral Physics, Planetary Geophysics and Seismology, Planetary Mineral Physics
Barometers behaving badly: Assessing the influence of analytical and experimental uncertainty on clinopyroxene thermobarometry calculations at crustal conditions
Published: 2022-12-01
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics, Volcanology
The composition of clinopyroxene and Clinopyroxene-Liquid (Cpx-Liq) pairs are frequently used to calculate crystallization/equilibration pressures in igneous systems. While canonical uncertainties are often assigned to calculated pressures based on fits to calibration or test datasets, the sources of these uncertainties (and thus ways to reduce them) have not been rigorously assessed. We show [...]
Comparative study of alteration sequences in pegmatitic aluminium phosphates
Published: 2022-09-29
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics, Other Earth Sciences
Aluminium phosphates are mineral phases commonly occurring in rare-element pegmatites that record initial magmatic crystallization, metasomatic and hydrothermal replacements and precipitation and low-temperature alteration. Here we perform a comparative mineralogical study between several localities to assess similarities and variations in these parageneses and establish a general alteration [...]
Characterisation of phosphate mineralogy in Montebras-en-Soumans Pegmatite, Massif Central, France
Published: 2022-09-22
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics
Montebras-en-Soumans pegmatitic cupola hosts large pods of phosphate composed of primary amblygonite-montebrasite. These aluminium phosphate masses are considerably altered by post-magmatic processes producing a number of secondary metasomatic hydrothermal phosphates (lacroixite, wardite, morinite, viitaniemiite, apatite, triplite, eosphorite) and low-temperature phosphates (apatite, crandallite, [...]
Time-resolved infrared stimulated luminescence of the blue and yellow-green emissions – insights into charge recombination in chemically and structurally different alkali feldspars
Published: 2022-08-23
Subjects: Earth Sciences, Mineral Physics
Time-resolved luminescence measurements can be used to explore luminescence processes in minerals and the defects involved. It has also been applied to feldspars and knowledge has been gained regarding potential crystal defects associated with luminescence productions in these minerals, but also regarding processes governing electron-hole recombination leading to luminescence emission. Here we [...]
Probabilistic Assessment of Antarctic Thermomechanical Structure: Impacts on Ice Sheet Stability
Published: 2022-05-19
Subjects: Earth Sciences, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics, Statistical Methodology
Uncertainty in present-day glacial isostatic adjustment (GIA) rates represents at least 44% of the total gravity-based ice mass balance signal over Antarctica. Meanwhile, physical couplings between solid Earth, sea level and ice dynamics enhance the dependency of the spatiotemporally varying GIA signal on three-dimensional variations in mantle rheology. Improved knowledge of thermomechanical [...]
CCC - integrated multiscale study of salt cavern abandonment in the Netherlands
Published: 2022-03-24
Subjects: Geology, Geophysics and Seismology, Materials Science and Engineering, Mineral Physics, Mining Engineering, Other Earth Sciences, Tectonics and Structure
The KEM-17 project of the Dutch State Supervision of Mines presented a critical review of concepts of cavern abandonment and related science. It recommended that analyses of cavern abandonment are done as an integrated project, addressing (i) micro-scale physical processes, (ii) cavern scale models based on field scale experiments and numerical models, (iii) the salt dome scale, to model the far [...]
Thermochemical structure and evolution of cratonic lithosphere in central and southern Africa
Published: 2021-12-10
Subjects: Earth Sciences, Geochemistry, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics, Tectonics and Structure
The thermochemical structure of the subcontinental mantle holds information on its origin and evolution that can inform energy and mineral exploration strategies, natural hazard mitigation and evolutionary models of the Earth. However, imaging the fine-scale thermochemical structure of continental lithosphere remains a major challenge. Here we combine multiple land and satellite datasets via [...]
Reproducibility in subsurface geoscience
Published: 2021-10-27
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Environmental Education, Environmental Health and Protection, Environmental Indicators and Impact Assessment, Environmental Monitoring, Environmental Sciences, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Hydrology, Mineral Physics, Natural Resource Economics, Natural Resources and Conservation, Natural Resources Management and Policy, Oil, Gas, and Energy, Other Earth Sciences, Other Environmental Sciences, Paleobiology, Paleontology, Sedimentology, Soil Science, Speleology, Stratigraphy, Sustainability, Tectonics and Structure, Volcanology, Water Resource Management
Reproducibility, the extent to which consistent results are obtained when an experiment or study is repeated, sits at the foundation of science. The aim of this process is to produce robust findings and knowledge, with reproducibility being the screening tool to benchmark how well we are implementing the scientific method. However, the re-examination of results from many disciplines has caused [...]
Improving the reliability of Fe- and S-XANES measurements in silicate glasses: Correcting beam damage and identifying Fe-oxide nanolites in hydrous and anhydrous melt inclusions
Published: 2021-10-19
Subjects: Geochemistry, Geology, Mineral Physics, Physical Sciences and Mathematics, Volcanology
The redox state of silicate melts influences crystallization, element partitioning, and degassing behavior. Synchrotron-based micro-X-ray absorption near edge structure (μXANES) spectroscopy has emerged as a powerful tool for determining redox conditions through the direct measurement of speciation of multivalent elements such as iron and sulfur in silicate glasses. In particular, the high [...]
An anisotropic equation of state for high pressure, high temperature applications
Published: 2021-09-25
Subjects: Condensed Matter Physics, Geophysics and Seismology, Materials Science and Engineering, Mineral Physics, Physical Sciences and Mathematics, Planetary Geophysics and Seismology, Planetary Mineral Physics
This paper presents a strategy for consistently extending isotropic equations of state to model anisotropic materials over a wide range of pressures and temperatures under nearly hydrostatic conditions. The method can be applied to materials of arbitrary symmetry. The paper provides expressions for the deformation gradient tensor, the lattice parameters, the isothermal elastic compliance tensor [...]
Shear-wave Anisotropy in the Earth’s Inner Core
Published: 2021-09-17
Subjects: Earth Sciences, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics
Earth’s inner core anisotropy is widely used to infer the deep Earth's evolution and present dynamics. Many compressional-wave anisotropy models have been proposed based on seismological observations. In contrast, inner-core shear-wave (J-wave) anisotropy – on a par with the compressional-wave anisotropy – has been elusive. Here we present a new class of the J-wave anisotropy observations [...]
Safety and Belonging in the Field: A Checklist for Educators
Published: 2021-08-19
Subjects: Atmospheric Sciences, Biogeochemistry, Climate, Cosmochemistry, Earth Sciences, Education, Environmental Education, Environmental Health and Protection, Environmental Indicators and Impact Assessment, Environmental Monitoring, Environmental Sciences, Environmental Studies, Fresh Water Studies, Geochemistry, Geographic Information Sciences, Geography, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Higher Education, Human Geography, Hydrology, Life Sciences, Meteorology, Mineral Physics, Natural Resource Economics, Natural Resources and Conservation, Natural Resources Management and Policy, Nature and Society Relations, Oceanography, Oceanography and Atmospheric Sciences and Meteorology, Oil, Gas, and Energy, Other Earth Sciences, Other Environmental Sciences, Other Geography, Other Oceanography and Atmospheric Sciences and Meteorology, Other Planetary Sciences, Outdoor Education, Paleobiology, Paleontology, Physical and Environmental Geography, Physical Sciences and Mathematics, Planetary Biogeochemistry, Planetary Geochemistry, Planetary Geology, Planetary Geomorphology, Planetary Geophysics and Seismology, Planetary Glaciology, Planetary Hydrology, Planetary Mineral Physics, Planetary Sciences, Planetary Sedimentology, Remote Sensing, Sedimentology, Social and Behavioral Sciences, Soil Science, Spatial Science, Speleology, Stratigraphy, Sustainability, Tectonics and Structure, Volcanology, Water Resource Management
Ensuring taught fieldwork is a positive, generative, collective, and valuable experience for all participants requires considerations beyond course content. To guarantee safety and belonging, participants’ identities (backgrounds and protected characteristics) must be considered as a part of fieldwork planning and implementation. Furthermore, getting fieldwork right is an important step in [...]