Preprints
Filtering by Subject: Mineral Physics
Timing of Martian Core Formation from Models of Hf–W Evolution Coupled with N-body Simulations
Published: 2021-06-04
Subjects: Geochemistry, Mineral Physics, Planetary Sciences
Determining how and when Mars formed has been a long-standing challenge for planetary scientists. The size and orbit of Mars are difficult to reproduce in classical simulations of planetary accretion, and this has inspired models of inner solar system evolution that are tuned to produce Mars-like planets. However, such models are not always coupled to geochemical constraints. Analyses of Martian [...]
Assessment of quartz grain growth and the application of the wattmeter to predict recrystallized grain sizes
Published: 2020-12-04
Subjects: Geology, Mineral Physics, Tectonics and Structure
We investigated relationships between the recrystallized grain size and stress in experimentally deformed water-added quartz aggregates. For stresses >100 MPa there is a variation in the measured recrystallized grain size for a given stress. We found this variation correlates with a change in the c-axis fabric in general shear experiments, where samples with larger recrystallized grain sizes for [...]
The miscibility of Calcium Silicate Perovskite and Bridgmanite: A single phase perovskite in hot, iron-rich regions
Published: 2020-11-02
Subjects: Earth Sciences, Mineral Physics, Physical Sciences and Mathematics
Calcium silicate perovskite and bridgmanite are two phases believed to coexist throughout the lower mantle, which at some temperature, at least theoretically, dissolve into each other to form a single perovskite solid solution (CaxMg1-xSiO3). This may have large seismic and geochemical implications due to the changes in density, elasticity and element partition coefficients between single and [...]
High-Pressure Deformation of Iron–Nickel–Silicon Alloys and Implications for Earth’s Inner Core
Published: 2020-10-21
Subjects: Earth Sciences, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics
Earth’s inner core exhibits strong seismic anisotropy, often attributed to the alignment of hexagonal close-packed iron (hcp-Fe) alloy crystallites with the Earth’s poles. How this alignment developed depends on material properties of the alloy and is important to our understanding of the core’s crystallization history and active geodynamical forcing. Previous studies suggested that hcp-Fe is [...]
Quantification of non-linear multiphase flow in porous media
Published: 2020-08-20
Subjects: Earth Sciences, Engineering, Hydrology, Life Sciences, Medicine and Health Sciences, Mineral Physics, Physical Sciences and Mathematics
We measure the pressure difference during two-phase flow across a sandstone sample for a range of injection rates and fractional flows of water, the wetting phase, during an imbibition experiment. We quantify the onset of a transition from a linear relationship between flow rate and pressure gradient to a non-linear power-law dependence. We show that the transition from linear (Darcy) to [...]
Explaining the dependence of M-site diffusion in forsterite on silica activity: a Density Functional Theory approach
Published: 2020-07-29
Subjects: Earth Sciences, Mineral Physics, Physical Sciences and Mathematics
Experimentally silica activity (aSiO2) has been shown to have an effect on Mg diffusion in forsterite but without any obvious mechanism. We calculated the effects of aSiO2 and aluminium content (the main contaminant in the experimental studies), and their co-effect, on Mg diffusion in forsterite, using thermodynamic minimisations of defect formation energies (calculated using Density Functional [...]
Dislocation interactions in olivine control postseismic creep of the upper mantle
Published: 2020-06-29
Subjects: Condensed Matter Physics, Earth Sciences, Geology, Mineral Physics, Physical Sciences and Mathematics, Physics, Tectonics and Structure
Changes in stress applied to mantle rocks, such as those imposed by earthquakes, induce a period of evolution in viscosity and microstructure. This transient creep is often modelled based on stress transfer among slip systems due to grain interactions. However, recent experiments have demonstrated that the intragranular accumulation of stresses among dislocations is the dominant cause of strain [...]
Seismological Expression of the Iron Spin Crossover in Ferropericlase in the Earth’s Lower Mantle
Published: 2020-06-29
Subjects: Earth Sciences, Geochemistry, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics, Physics, Quantum Physics, Tectonics and Structure
The two most abundant minerals on Earth which together make up over 90% of the Earth’s lower mantle are (Mg,Fe)O-ferropericlase (Fp) and (Mg,Fe)SiO3-bridgmanite (Bm). Iron in Fp undergoes a high-spin to low-spin (HS-LS) crossover that influences density, viscosity, elasticity, thermal conductivity, and elemental partitioning, however, the predicted effects of this transition are not apparent in [...]
Rates of olivine grain growth during dynamic recrystallization and post-deformation annealing
Published: 2020-06-22
Subjects: Earth Sciences, Geology, Mineral Physics, Physical Sciences and Mathematics, Tectonics and Structure
We performed deformation and grain growth experiments on natural olivine aggregates with moderate olivine water contents (COH = 600±300 ppm H/Si) at 1000-1200°C and a confining pressure of 1400±100 MPa. Our experiments differ from published grain growth studies in that most were: 1) conducted on natural olivine cores rather than hot-pressed aggregates, and 2) dynamically recrystallized prior to [...]
International disparities in open access practices of the Earth Sciences community
Published: 2020-03-31
Subjects: Biogeochemistry, Cosmochemistry, Earth Sciences, Geochemistry, Geology, Geomorphology, Geophysics and Seismology, Glaciology, Hydrology, Library and Information Science, Mineral Physics, Other Earth Sciences, Paleobiology, Paleontology, Physical Sciences and Mathematics, Sedimentology, Social and Behavioral Sciences, Soil Science, Speleology, Stratigraphy, Tectonics and Structure, Volcanology
Short communication on international disparities in open access practices of the Earth Sciences community
The mechanism of Mg diffusion in forsterite and the controls on its anisotropy
Published: 2020-03-31
Subjects: Earth Sciences, Mineral Physics, Physical Sciences and Mathematics
Mg diffusion is important for explaining many rheological properties in forsterite but its mechanism is unknown. Without knowing a mechanism the effect of variables such as pressure are hard to constrain. In this study we used Density Functional Theory (DFT) to calculate the diffusivity of Mg vacancies and interstitials in forsterite and thus the diffusion rate of Mg in forsterite. We predict [...]
Notes on the creation and manipulation of solid solution models
Published: 2019-12-04
Subjects: Chemistry, Earth Sciences, Materials Chemistry, Mineral Physics, Physical Sciences and Mathematics
A large class of solid solution models are built on the premise that exchange of chemical species takes place on a finite number of unique sites, and that the thermodynamic properties of the solution are a function of the proportions of species occupying each of the sites. The site-occupancy spaces spanned by such models are geometrically equivalent to convex polytopes, n-dimensional [...]
Ultramafic rock carbonation: Constraints from listvenite core BT1B, Oman Drilling Project
Published: 2019-11-14
Subjects: Earth Sciences, Geochemistry, Geology, Mineral Physics, Other Earth Sciences, Physical Sciences and Mathematics
The occurrence of the quartz–carbonate alteration assemblage (listvenite) in ophiolites indicates that ultramafic rock represents an effective sink for dissolved CO2. However, the majority of earlier studies of ultramafic rock carbonation had to rely on the surface exposure of reaction textures and field relationships. Here we present the first observations on ultramafic rock alteration obtained [...]
The Fate of Carbon during Earth’s Core–Mantle Differentiation
Published: 2019-11-14
Subjects: Earth Sciences, Geochemistry, Mineral Physics, Physical Sciences and Mathematics
Carbon is an essential element for the existence and evolution of life on Earth, constitutes up to 50% of dry biomass, and is likely a requirement for all life in the universe. Its high abundance in Earth’s crust and mantle (the Bulk Silicate Earth, BSE) is surprising because carbon is strongly siderophile (metal-loving) and should have segregated almost completely into Earth’s core during [...]
The variation and visualisation of elastic anisotropy in rock-forming minerals
Published: 2019-10-31
Subjects: Earth Sciences, Geochemistry, Geology, Geophysics and Seismology, Mineral Physics, Physical Sciences and Mathematics, Tectonics and Structure
All minerals behave elastically, a rheological property that controls their ability to support stress, strain and pressure, the nature of acoustic wave propagation and influences subsequent plastic (i.e. permanent, non-reversible) deformation. All minerals are intrinsically anisotropic in their elastic properties – that is, they have directional variations that are related to the configuration [...]